摘要
介绍了双乙二酸硼酸锂(L iBOB)的电化学性能、在高温下的热稳定性,以及其最新的合成方法、提纯方法和检测方法。报道了有关L iBOB基电解质性能方面的研究现状,包括电极与电解质界面间的固态电解质界面膜(SEI)的形成原因、形成机理及主要成分,电解质中常用溶剂的性质及L iBOB在多元溶剂体系中的性能,以及各种正极材料在L iBOB基电解质中的稳定性。简要指明了L iBOB基电解质的应用前景和发展方向。
Electrochemical performance, thermal stability at high tempreture, the latest synthetical method, purification method,and detection method of lithium his ( oxalatc ) borate (LiBOB) were introduced. Research status about performances of LiBOB based electrolytes, including formative reasons, mechanism, and main composition of solid electrolyte interface (SEI) film formed between electrode and electrolyte intcrphase, properties of common solvents, performances of LiBOB used in multidimensional solvent system, and stability of various cathode materials used in LiBOB-bascd electrolytes were also reported. Application prospect and development direction of LiBOP-based electrolytes were pointed out briefly.
出处
《无机盐工业》
CAS
北大核心
2009年第10期11-14,共4页
Inorganic Chemicals Industry
基金
辽宁省教育厅基金项目(2008379)
辽宁省自然科学基金项目(20082187)
关键词
双乙二酸硼酸锂
锂盐
液体电解质
lithium bis ( oxalate ) borate
lithium salt
liquid electrolyte