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双乙二酸硼酸锂在液态电解质中的研究进展 被引量:1

Reaserch progress of lithium bis(oxalate) borate used in liquid electrolyte
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摘要 介绍了双乙二酸硼酸锂(L iBOB)的电化学性能、在高温下的热稳定性,以及其最新的合成方法、提纯方法和检测方法。报道了有关L iBOB基电解质性能方面的研究现状,包括电极与电解质界面间的固态电解质界面膜(SEI)的形成原因、形成机理及主要成分,电解质中常用溶剂的性质及L iBOB在多元溶剂体系中的性能,以及各种正极材料在L iBOB基电解质中的稳定性。简要指明了L iBOB基电解质的应用前景和发展方向。 Electrochemical performance, thermal stability at high tempreture, the latest synthetical method, purification method,and detection method of lithium his ( oxalatc ) borate (LiBOB) were introduced. Research status about performances of LiBOB based electrolytes, including formative reasons, mechanism, and main composition of solid electrolyte interface (SEI) film formed between electrode and electrolyte intcrphase, properties of common solvents, performances of LiBOB used in multidimensional solvent system, and stability of various cathode materials used in LiBOB-bascd electrolytes were also reported. Application prospect and development direction of LiBOP-based electrolytes were pointed out briefly.
出处 《无机盐工业》 CAS 北大核心 2009年第10期11-14,共4页 Inorganic Chemicals Industry
基金 辽宁省教育厅基金项目(2008379) 辽宁省自然科学基金项目(20082187)
关键词 双乙二酸硼酸锂 锂盐 液体电解质 lithium bis ( oxalate ) borate lithium salt liquid electrolyte
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参考文献25

  • 1Larush - Asraf L, Biton M, Teller H, et al. On the electrochemical and thermal behavior of lithium his (oxalato) borate (LiBOB) solutions [ J ]. J. Power Source,2007,174 ( 2 ) :400 - 407.
  • 2Zinigrad E, Larush - Asraf L, Salitra G, et al. On the thermal behavior of Li bis (oxalato) borate LiBOB [ J ]. Thermochimica Acta, 2007,457 ( 1/2 ) :64 - 69.
  • 3Xu K, Angell C A. LiBOB and its derivatives weakly coordination anions and the exceptional conductivity of their nonaqueous solutions [ J ]. Electroehem. Solid - State Lett. ,2001,4 ( 1 ) : E1 - E4.
  • 4轩小朋,赵扬,王键吉.LiBOB的结构、性质和在锂离子蓄电池中的应用[J].电源技术,2006,30(11):943-946. 被引量:8
  • 5Wang Sai, Qiu Weihua, Guan Yunlong,et al. Electrochemical characteristics of LiMx Fe1-x PO4 cathode with LiBOB based electrolytes [ J ]. Electrochimica Acta, 2007,52 ( 15 ) : 4907 - 4910.
  • 6Wang Sai, Qiu Weihua, Li Tao,et al. Properties of lithium bis (oxalate)borate (LiBOB) as a lithium salt and cycle performance in LiMn2 O4 half cell [ J ]. Electrochemical Science, 2006 ( 1 ) : 250 - 257.
  • 7Xu K,Zhang S S,Poese B A. Lithium bis(oxalate) borate stabilizes graphite anode in propylene carbonate [ J ]. Electrochemical and Solid - State Letters ,2002,5 ( 11 ) :A259 - A262.
  • 8Zhang S S, Xu K, Jow T R. An improved electrolyte for the LiFePO4 cathode working in a wide temperature range [ J ]. Journal of Power Sources,2006,159 (2) :702 - 707.
  • 9Chen Zonghai, Liu W Q, Liu J, et al. LiPF6/LiBOB blend salt electrolyte for high - power lithium-ion batteries [ J ]. Electrochimica Acta,2006,51 (16) : 3322 - 3326.
  • 10Lischka U, Wietelman U, Wegner M. Lithium bis(oxalate) borate, the production thereof and its use as a conducting salt: DE, 19829030[ P]. 2001 -04 - 18.

二级参考文献78

  • 1余碧涛,李福燊,仇卫华,李丽芬.锂离子电池新型电解质锂盐的研究进展[J].电池,2004,34(6):446-448. 被引量:13
  • 2薛照明,陈春华.锂离子电池非水电解质锂盐的研究进展[J].化学进展,2005,17(3):399-405. 被引量:19
  • 3宁英坤,余碧涛,李福燊,仇卫华.LiBOB/PC电解液的性能研究[J].电池,2006,36(2):84-86. 被引量:9
  • 4Heider U,Oesten R,Jungnitz M.Challenge in manufacturing elec -trolyte solutions for lithium and lithium ion batteries quality control and minimizing contamination level[J].J Power Sources,1999,81 -82:119-122.
  • 5Mario W,Margret W M,Sandra S,et al.Formation and kinetics of carbon materials in LiBOB-based electrolytes[A].Abstract of 207th ECS Meeting[C].Quebec,2005.
  • 6Zavalij P Y,Yang S,Whittingham M S.Structures of potassium,sodium and lithium bis(oxalato)borate salts from powder diffraction data[J].Acta Cryst,2003,B59(6):753-759.
  • 7化学工业部化学试剂质量监测中心.化学试剂标准大全[M].Beijing(北京):Chemical Industry Press(化学工业出版社),1995.
  • 8ZHOU Tong-hui(周同慧),WANG Er-kang(汪尔康),LU Wan-zhen(陆婉珍),et al.分析化学手册[M].Beijing(北京):Chemical Industry Press(化学工业出版社),1997.
  • 9LIYue-ping(李跃平).ICP—AES法测定纯铝中微量B、V、Li、Be、Ga的方法研究[J].分析试验室,2004,23(1):339-341.
  • 10ZHONG Pei-heng(钟佩珩),GUO Xuan-hua(郭璇华).分析化学[M].Beiiing(北京):Higher Education Press(高等教育出版社),1994.

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