摘要
采用电化学循环伏安法和荧光光谱研究了系列Ｏｓ（Ⅱ）配合物的电化学性质及分子结构对其电子能级结构的影响．
The effects of molecular structure on the electrochemical properties and the electronic structure of four Os(Ⅱ) complexes have been explored by cyclic voltammetry and fluorescence spectra. The results indicate that the oxidation and reduction properties and the electronic energy level structure of the complexes can be changed by either introducing different substituents into the bipyridine ligand or replacing the bipyridine ligand with phenanthroline. The above conclusion were confirmed by the photospectroscopy measurements.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第10期1671-1673,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
电化学
分子结构
电子结构
锇配合物
Electrochemistry, Redox, Molecular structure, Electronic structure
