摘要
在反应机理的指导下，采用醋酐过量抑制生成乙醛副反应的发生，研究了以苯磺酸为催化剂的二醋酸亚乙酯裂解制醋酸乙烯的反应动力学规律，得到描述该反应过程的动力学数学模型。
The kinetics of thermal decomposition of the ethylidene diacetate to form vinyl acetate in the presence of benzene sulfuric acid catalyst has been studied. The exponential rate equation of the process obtained from experimental data is r=2.069×10 10 exp (-97 8008.314×T)c a 0 -0.066 (1-x) 0.933 5 -2.604×10 10 exp (-96 7608.314×T)c a 0 -0.407 x 0.592 6 .
出处
《华东理工大学学报（自然科学版）》
CAS
CSCD
北大核心
1998年第5期605-609,共5页
Journal of East China University of Science and Technology
关键词
二醋酸亚乙酯
醋酸乙烯
苯磺酸
动力学
裂解
ethylidene diacetate
vinyl acetate
benzene sulfuric acid
kinetics
simplex method
