摘要
以ｃｉｓ－１，２－二氰基乙烯－１，２二硫醇钠和二氯·邻菲啉合镉（Ⅱ）为原料合成了标题配合物，并经元素分析、摩尔电导、红外光谱、电子吸收和发射光谱表征，其结构为四配位的电中性配合物，易溶于二甲基亚砜、二甲基甲酰胺、吡啶，难溶于苯、乙醚和水。测量了掺杂有标题配合物的ＣｄＳ－ＰＶＡ复合膜的暗态导电性和光电导性，研究了标题配合物对ＣｄＳ的光敏化作用与其电子光谱间的关系。
The title complex Cd(mnt)(phen) (mnt, 1,2-dicyano-ethylene dithiolate. phen, 1,10-phenanthroline) was synthesized by reaction of Na 2(mnt) with Cd(phen)Cl 2. The elecmental analysis, molar conductivities, IR, UV-Vis, and fluorescence spectra showed the complex as having electroneutrality with approximate square planar structure. Cd(mnt)(phen) is easy dissolved in DMSO, DMF and Py, and insoluble benzene, ether and water. The dark conductivity and photoconductivity of CdS doped with Cd(mnt)(phen). The Correlation between photosensitization of complex Cd(mnt)(phen) to CdS and Its electronic spectra was studied.
出处
《河南科学》
1998年第4期399-403,共5页
Henan Science
基金
国家自然科学基金
配位化学国家重点实验室研究基金
关键词
二硫纶
邻菲罗啉
镉
合成
光敏性
配合物
Dithiolene
Phenanthroline
Cadmium
Synthesis
Photosensitivity
