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改性球形微晶石墨用作锂离子电池负极材料的研究 被引量:8

Study on Modified Spherical Microcrystalline Graphite as Anode Materials for Li-ion Batteries
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摘要 为了改善用作锂离子电池负极材料的球形微晶石墨的电化学性能,采用液相浸渍工艺在石墨颗粒表面上包覆一层树脂炭.结果表明:经包覆后,石墨颗粒表面更为光滑,其首次充放电循环效率从包覆前的81.0%提高到了92.7%,且首次可逆比容量也有所增加. To improve the electrochemical performance of spherical microcrystalline graphite (SMCG) as anode material for Li-ion battery, resin was coated on the surface of SMCG by means of liquid impregnation. The result showed that the surface of SMCG became smoother after the coating. The coating improved the cycle efficiency of material, from 81.0% before coating to 92.7% after coating.
出处 《湖南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2009年第11期44-46,61,共4页 Journal of Hunan University:Natural Sciences
基金 国家自然科学基金资助项目(50872032)
关键词 包覆 球形微晶石墨 负极材料 锂离子电池 coatings spherical microcrystalline graphite anode material li-ion battery
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  • 1HERSTEDT A, FRANSSON L, EDSTROM K. Rate capability of natural swedish graphite as anode material in Li-ion batteries[J]. Journal of Power Sources, 2003,124 (1) : 191-196.
  • 2ZAGHIB K, SONG X, GUERFI A, et al. Purification process of natural graphite as anode for Li-on batteries: Chemical versus thermal[J]. Journal of Power Sources, 2003, 119 (1):8-15.
  • 3YOSHIO M, WANG H Y, FUKUDA K, etal. Effect of carbon coating on electrochemistry performance of treated natural graphite as lithium-ion battery anode material[J]. Journal of the Electrochemical Society, 2000,147(5) : 1245-1250.
  • 4HONGYU W, YOSHIO M. Carbon-coated natural graphite prepared by thermal vapor decomposition process, a candidate anode material for lithium-ion battery[J]. Journal of Power Sources, 2001,93(1/2) : 123 - 129.
  • 5WANG G P, ZHANG B L, YUE M,etal. A modified graphite anode with high initial efficiency and excellent cycle life expectation[J]. Solid State Ionics, 2005,176(9/10) : 905-909.
  • 6HAN Y S, LEE J Y. Improvement on the electrochemical characteristics of graphite anodes by coating of the pyrolytic carbon using tumbling chemical vapor deposition[J]. Electrochimica Acta,2003,48(8) : 1073-1079.
  • 7ZHOU Y F, XIE S, CHEN C H. Pyrolytic polyurea encapsulated natural graphete as anode material for lithium ion batteries[J]. Electrochimica Acta, 2005,50(24): 4728-4735.
  • 8TATSUMI K, IWASHITA N, SAKAEBE H, et al. Influence of the graphitie structure on the electrochemical characteristics for the anode of secondary lithium batteties[J]. Journal of the Electrochemical Society, 1995,142(2) :716-722.
  • 9BESENHARD J O, WINTER M, YANG J,et al. Filming mecha- nism of lithium-carbon anode in organic and inorganic electrolytes [J]. Journal of Power Sources,1995,54(2):228-231.
  • 10AURBACH D. Review of selected electrode-solution interactions which determine the performance of Li and Li on batteries[J]. Journal of Power Sources, 2000,89(2) : 206- 218.

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