摘要
α-磷酸锆(α-Zr(HPO4)2·H2O,α-ZrP)、γ-磷酸锆(Zr(PO4)(H2PO4)·2H2O,γ-ZrP)及其衍生物由于在离子交换、质子传导、插层化学、催化、光化学、材料化学等领域有潜在的应用前景,因而引发了大量的研究工作。本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性,另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。
a-Zirconium phosphate （α-Zr（HPO4）2·H2O,α-ZrP）、γ--zirconium phosphate （Zr（PO4）（H2PO4）·2H2O,γ-ZrP）and their derivatives have attracted a lot of research attention in recent years due to their potential applications in the areas of ion exchange, proton conductivity, intercalation chemistry, catalysis, photochemistry and material chemistry. The mechanism, thermodynamics and kinetics of ion-exchange reactions between alkali, alkaline-earth and transition metal ions and zirconium phosphate and its derivatives are reviewed, progress in ion-exchange reaction between luminescent metal complex and zirconium phosphate is also discussed.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2009年第12期2536-2541,共6页
Progress in Chemistry
基金
西南大学科研基金项目(No.2007F005
08BSr01)资助
关键词
磷酸锆及其衍生物
离子交换性能
功能材料
zirconium phosphate and its derivatives
ion-exchange property
functional materials
