期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

硫醇作亲核试剂在有机合成中的应用 被引量：1

Application of Thiol in Organic Synthesis as Nucleophilic Reagent
下载PDF
导出
摘要 概括硫醇作为亲核试剂与环氧化合物和氮杂环丙烷类化合物加成反应、与酰氯、酸酐、酰胺、酯和羧酸的酰化反应及与醇和卤代烃的亲核取代反应。 The nucleophilic addition reaction of thiol and epoxide/aziridine, its acylation reaction with acylating reagents such as acyl chlorides, anhydrides, and so on and its nueleophilie substituted reaction with halides and alcohol were reviewed, respectively.
作者 赵辉 杨雪 于海丰
机构地区 鞍山师范学院化学系
出处 《辽宁化工》 CAS 2009年第12期903-906,共4页 Liaoning Chemical Industry
基金 鞍山市科委2007年基金(2007SF23) 鞍山师范学院2007年博士启动基金资助
关键词 硫醇 亲核试剂 亲核加成反应 亲核取代反应 Thiol Nucleophilic Reagent Nucleophilic Addition Reaction Nueleophilic Substituted Reaction
分类号 TQ227.1 [化学工程—有机化工]
  • 相关文献

参考文献38

  • 1Sartori G, Ballini R, Bigi F. et al. Protection ( and Deprotection) of Functional Groups in Organic Synthesis by Heterogeneous Catalysis[J]. Chem. Rev. 2004, 104:233 -236.
  • 2于海丰,侯冬岩,白殿罡.硫醇与α,β-不饱和羰基化合物的Michael加成反应的研究进展[J].鞍山师范学院学报,2007,9(6):22-25. 被引量：2
  • 3白殿罡,赵辉,于海丰.硫醇与α,β-不饱和羰基化合物的不对称Michael加成反应的研究进展[J].辽宁化工,2009,38(2):119-123. 被引量：1
  • 4Posner G H, Rogers D Z. Organic Reactions at Alumina Surfaces. Mild and Selective Opening of Epoxides by Alcohols, Thiols, Benzeneselenol, Amines, and Acetic Acid [ J ]. J. Am. Chem. Soc, 1977, 99:8 208 -8 215.
  • 5Guivisdalsky P N, Bittman R, Glycidyl Derivatives as Chiral C3 Synthons. Ring Opening Catalyzed by BF3 Etherate [ J]. J. Am. Chem. Soc, 1989, 111: 3 077-3 079.
  • 6Chini M, Crotti P, Giovani E. et al. Stereo - and Regioselective Metal Salt - Promoted Ring Opening of 1,2 - Epoxides with Thiols in Acetonitrile[ J ]. Synlett, 1992, 4 : 303 - 305.
  • 7Albanese D, Landini D, Penso M. Tetrabutylammonium Fluoride: A Powerful Catalyst for the Regioselective Opening of Epoxides with Thiols[J]. Synthesis ,1994, 1 : 34 -36.
  • 8Raubo P, Wicha J. Silica Gel catalyzed Addition of Benzenethiol to, α, β - Epoxyaikylsilane and Expoxide [ J ]. Synlett , 1993, 1 : 25 -26.
  • 9Chandrasekhar S, Reddy C R, Babu B N. et al. Highly efficient cleavage of epoxides catalyzed by B( C6F5 )3 [ J]. Tetrahedron Lett,2002, 43:3 801 -3 803.
  • 10Yadav J S, Reddy B V S, Baishya G. InCl3 - Catalyzed Highly Regioselective Ring Opening of Epoxides with Thiols [ J ]. Chem. Lett,2002,906 - 907.

二级参考文献46

  • 1于海丰,侯冬岩,白殿罡.硫醇与α,β-不饱和羰基化合物的Michael加成反应的研究进展[J].鞍山师范学院学报,2007,9(6):22-25. 被引量：2
  • 2Fluharty A L. In The Chemistry of the Thiol Group [ M ]. Patai, S. , Ed. ; Wiely: New York, 1974.
  • 3Naidu B N, Li W Y, Sorenson M E. et al. Organic reactions in frozen water: Michael addition of amines and thiols to the dehydroalanine side chain of nocathiacins [ J ]. Tetrahedron Lett. 2004, 45:1 059-1 063.
  • 4Trost B M, Keeley D E, New Synthetic Methods. Secoalkylative Approaeh to Grandisol[J]. J. Org. Chem. 1975, 40:2013 -2 013.
  • 5Cohen T, Mura A J, Shull D W. et al. Removal of Sulfur Groups from Molecules by Copper (I). Preparation of Sulfur- Substituted 1,3 - Dienes for the Diels - Alder Reaction1[J]. J. Org. Chem. 1976, 41 : 3 218 -3 221.
  • 6Bakuzis P, Bakuzis M L F. Oxidative Functionalization of the β- Carbon in α, 13 - Unsaturated Systems. Preparation of 3 - Phenylthio Enones, Acrylates, and Other Vinyl Derivatives [J]. J. Org. Chem. 1981,46:235-239.
  • 7Cherkauskas J P, Cohen T. Carbonyl - Protected B - Lithio Aldehydes and Ketones via Reductive Lithiation. A General Preparative Method for Remarkably Versatile Homoenolate Equivalents[J]. J. Org. Chem. 1992, 57 (1): 6-8.
  • 8Miyata O, Shinada T, Naito T. Asymmetric Construction of Two Contiguous Stereocenters by Diastereoface Differentiating Addition Reaction of Thiols to Chiral lmides: Formal Asymmetric Synthesis of ( - ) -Diltiazem[J]. Tetrahedron. 1997, 53:2 421 -2 438.
  • 9Lin C H, Yang K Shuo, PanJ F. et al. Diastereoselective conjugate addition of thiols to camphor pyrazolidinone derived chiral α, β - unsaturated carbonyls: synthesis of - mereaptocarboxylic acid derivatives[J]. Tetrahedron Lett. 2000, 41:6 815 -6 819.
  • 10Ozeki M, Nishide K, Teraoka F. et al. Diastereo- and enantioselective synthesis of anti - 1,3 - mercapto alcohols from α,β- unsaturated ketones via tandem Michael addition - MPV reduction[J].Tetrahedron: Asymmetry 2004, 15 : 895-907.

共引文献1

同被引文献4

引证文献1

二级引证文献2

辽宁化工
2009年 第12期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部