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PMo_(12)修饰Pt/C电极对甲醇的催化氧化研究 被引量:2

PMo_(12) modified Pt/C electrode and its electrocatalysis to methanol oxidation
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摘要 为了提高直接甲醇燃料电池阳极催化活性,通过浸渍法制备了PMo12修饰Pt/C电极,并采用粉末微电极技术比较研究了PMo12修饰Pt/C电极在硫酸溶液中的电化学性质及其对甲醇氧化反应的电催化性能。结果表明,甲醇在PMo12修饰Pt/C电极上的氧化速度能够明显提高。 In order to improve the electrocatalytic activity of the anode in the direct methanol fuel cell, PMo12 modified Pt/C electrode was successfully prepared by immersion. The elcctrochimical quality in the sulphuric acid solution and the electrocatalysis to the methol oxidation of PMo12 modified Pt/C electrode and unmodified Pt/C electrode were compared by the technique of power microelectrode. The results show that the rate of the methol oxidation on the PMo12 modified Pt/C electrode was largely increased.
出处 《电源技术》 CAS CSCD 北大核心 2010年第5期473-475,共3页 Chinese Journal of Power Sources
基金 塔里木大学校长基金(TDZKSS07012)
关键词 甲醇氧化 电催化 PMo12修饰 PT/C电极 methanol oxidation electrocatalysis PMo12 modified Pt/C electrode
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  • 1李长志,张颖,苏爱华,孙公权,杨维谦,陆天虹.质子交换膜燃料电池中氢电极和氧电极性能的研究[J].电源技术,1996,20(3):93-98. 被引量:11
  • 2DAM H E V, BEKKUM H V. Preparation of platinum on activated carbon [ J ]. J Catalysis, 1991,131:335 - 349.
  • 3ARICO A S, CRETI P, KIM H. Analysis of the electrochemical characteristics of a direct methanol fuel cell based on a Pt - Ru/C anode catalyst [ J ]. J Elecrtochem Soc, 1996,143 ( 12 ) : 3950 - 3959.
  • 4UCHIDA M, FUKUOKA Y, SUGAWARA Y. Improved preparation precess of very - low - platinum - lording electrodes for polymer electrolyte fuel cell [ J ]. J Elecrtochem Soc, 1998,145 ( 11 ) :3708 - 3715.
  • 5LEE S J,MUKERJEE S,MCBREEN J. Effects of Nation imperegnation on performances of PEMFC electrodes[ J ].Electrochimica Acta, 1998,43 (24) :3693 - 3701.
  • 6Visco S J, Mailhe C C, De Jonghe L C, et al. A novel class of orgaosulfur electrodes for energy storage[J]. J Electrochem Soc, 1989, 136 (3): 661-664.
  • 7Meilin L, Visco S J, De Jonghe L C. Novel solid redox polymerization electrodes: all-solid-state, thin-film, rechargeable lithium batteries[J]. J Electrochem Soc, 1991, 138 (7) : 1 891-1 895.
  • 8Meilin L, Visco S J, De Jonghe L C. Novel solid redox polymerization electrodes: electrochemical properties[J]. J Electrochem Soc, 1991,138 (7): 1 896-1 901.
  • 9Sotomura T, Tatsuma T, Oyama N. An organosulfur polymer cathode with a high current capability for rechargeable batteries[J]. J Electrochem Soc, 1996,143 (10): 3 152-3 157.
  • 10Shouji E, Buttry D A. An investigation of the effect of pyridine derivatives on the oxidative polymerization process of 2,5-dimercapto-1,3,4-thiadiazole and its dissulfide dimer [J]. J Phys chem B, 1998, 102 (8): 1 444-1 449.

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