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活性炭吸附Zn(Ⅱ)的热力学与机理研究 被引量:21

STUDY ON MECHANISM AND THERMODYNAMICSE OF Zn2+ ADSORPTION FROM AQUEOUS SOLUTION BY ACTIVED CARBON
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摘要 本文研究了水溶液中活性炭吸附Zn2+的热力学特性及其机理,测定了不同温度下的吸附等温线。结果表明:在稀溶液中吸附Zn2+符合Langmuir模型;活性炭吸附Zn2+时可能主要是以水合Zn(H2O)2+n形式被吸附的;活性炭表面存在含氧官能团的吸附活性中心;由于吸附水合Zn2+与炭表面含氧官能团之间相互作用,导致水分子的脱附及H+的产生,使其热力学函数ΔS0增加。 The thermodynamic characteristics and the mechanism of Zn2+adsorption by activated carbon in aqueous solution were studied and the adsorption isotherm line at different temperature were delermined in this paper. the results showed that the Zn2+adsorption in dilute solution can coincide with the Langmuir model; Zn2+ is adsorbed by activated carbon mainly in the form of hyarated Zn(H2O)2+n;the adsorption activation center of oxygen-containing function group existed in activate carbon surface; owing to the interaction between adsorption hydrated Zn2+ and oxygen-containing function group on carbon surface, the desorbing of water molecules and H+ formation make the thermodynamic function S0 increasing.
出处 《水处理技术》 CAS CSCD 1999年第2期103-107,共5页 Technology of Water Treatment
关键词 活性炭 吸附热力学 锌离子 机理 水溶液 activated carbon, adsorption Zn2+, adsorption thermodynamics
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参考文献4

  • 1陈禹银,高等学校化学学报,1993年,14卷,1432页
  • 2耿信笃,中国科学.B,1988年,14卷,571页
  • 3赵振国,化学学报,1985年,43卷,813页
  • 4周定,环境化学,1983年,2卷,3期,19页

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