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ZnO粒径对MC尼龙/纳米ZnO复合材料力学性能的影响

Effect of ZnO Parameters on the Mechanical Properties of MC Nylon 6/ZnO Nanocomposites
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摘要 用三种粒径范围的纳米ZnO合成MC尼龙/ZnO复合材料。考察了纳米ZnO的粒径对复合材料力学性能和在复合材料中的分散状况的影响。研究表明,平均粒径为30nm的ZnO合成的MC尼龙/纳米ZnO复合材料中ZnO粒子达到纳米级分散,粒子分布均匀,ZnO对MC尼龙的力学性能提高幅度最大,增强增韧作用非常明显;平均粒径为200nm的纳米ZnO在复合材料中,虽然粒径较大,但分散较均匀,无明显团聚,ZnO对MC尼龙的力学性能也有一定的提高,但提高幅度不大;平均粒径为60nm的ZnO分散难度大,ZnO在复合材料中既有小颗粒的分散,也有大颗粒的团聚体,使材料的力学性能明显不如前两种复合材料。 MC nylon 6/ZnO Nanocomposites were prepared with three kinds of particle size of nano-ZnO. Effect of the nano-ZnO size on the mechanical properties of nanocomposites and the dispersion of nano-ZnO within nanocomposites were studied. When the average particle size of ZnO is 30 nm,the ZnO particle dispered uniformly and the mechanical properties of the nanocomposites enlarged obviously,meanwhile strength and toughness function were increased greatly. It is found that the mechanical properties of the MC nylon filled with the 200 nm nano-ZnO are increased slightly,the particles disperse uniformly and no aggregation appears. When the 60 nm nano-ZnO is added,the mechanical properties are worse than the above two nanocomposites,the small particle and aggregated particle coexit.
作者 周莉 田彦文
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2010年第5期43-46,共4页 Polymer Materials Science & Engineering
基金 国家自然科学基金资助项目(50174015)
关键词 粒径 MC尼龙 纳米ZNO 力学性能 particle size MC nylon 6 nano-ZnO mechanical properties
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参考文献9

  • 1周莉,臧树良,张建中,田彦文.MC尼龙6/ZnO纳米复合材料的一步合成与性能[J].高分子材料科学与工程,2009,25(5):12-14. 被引量:2
  • 2周莉,田彦文,臧树良,张建中.纳米ZnO对MC尼龙结构和性能的影响[J].复合材料学报,2007,24(2):68-72. 被引量:25
  • 3JIANG T, WANG Y H, YEH J T, et al. Study on solvent permeation resistance properties of nylon6/clay nanocomposite [J ]. Eur. Polym. J., 2005, 41 : 459-466.
  • 4FORNES T D, PAUL D R. Structure and propertie of nanocomposite base on nylon-11 and nylon-12 compared with those based on nylon-6 [J]. Macromolecunles, 2004, 37: 7698-7709.
  • 5DONG W F, LIU Y Q, ZHANG X H, et al. Prepareation of high barrier and exfoliated-type nylon-6/uhrafine full-vulcanized powdered rubber/clay nanocomposites[J ]. Macrornolecunles, 2005, 38: 4551- 4553.
  • 6KOJIMA Y, USUKI A, KAWASUMI M, et al. Mechanical properties of nylon6-clay hybrid[J]. Matex. Res.,1993, 8(5):1185-1188.
  • 7LIU L M, QI Z N, ZHU X G. Studies on nylon6/chy nanocomposites by melt-interca/ation process [J].J. Appl. Polym. Sci., 1999, 71: 1133-1135.
  • 8QU L W, VECA L M, LIN Y, et al. Soluble nylon-funetionalized carbon nanotubes from anionic ring-opening polymerization from nanotube surface[J]. Macromolecules. 2005, 38: 10328-10331.
  • 9ZHENG J R, RICHARD W, SIEGEL C, et al. Polymer crystalline structure and rnorphology changes in nylon-6/ZnO nanocomposites [J]. J. Polym. Sci. Part B: Polym. Phys., 2003, 41 (11): 1033- 1050.

二级参考文献23

  • 1肖安国,张儒祥.几种纳米/PA6复合材料摩擦及加工性能研究[J].湖南文理学院学报(自然科学版),2005,17(2):31-33. 被引量:9
  • 2张士华,陈光,崔崇,米成,顾金萍,于静静.偶联剂处理对玻璃纤维/尼龙复合材料力学性能的影响[J].复合材料学报,2006,23(3):31-36. 被引量:67
  • 3周莉,田彦文,臧树良,张建中.纳米ZnO对MC尼龙结构和性能的影响[J].复合材料学报,2007,24(2):68-72. 被引量:25
  • 4KOJIMA Y, USUKI A, KAWASUMI M, et al. Mechanical pmpertiesof nylon 6-clay hybrid[J]. Mater. Res., 1993, 8(5): 1185-1188.
  • 5LIU L M, QI Z N, ZHU X G. Studies on nylon 6/clay nanocomposites by melt-intercalation process[J]. Appl. Polym. Sci. , 1999, 71: 1133-1135.
  • 6ZHENG J R, RICHARD W, SIEGEL C, et al. Polymer crystalline structure and morphology changes in nylon-6/ZnO nanocomposites [J]. J. Polym. Sci. Part B: Polym. Phys., 2003, 1(41):1033- 1050.
  • 7QU L W, VECA M L, LIN Y, et al. Soluble nylon-functionalized carbon nanotubes from anionic ring-opening polymerization from nanotube surface[J ]. Macromol., 2005, 38 : 10328-10331.
  • 8JIANG T WANG, Y H, YEH J T, et al. Study on solvent permeation resistance properties of nylon6/clay nanoeomposite [ J ]. Eur. Polym., 2005, 41 : 459-466.
  • 9Fomes T D, Paul D R. Structure and properties of nanocomposite base on nylon-lland nylon-12 compared with those based on nylon-6 [J]. Macromol. , 2004, 37: 7698-7709.
  • 10DONG W F, LIU Y Q, ZHANG X H, et al. Prepareation of high barrier and exfoliated-type nylon-6/ultrafine full-vulcanized powdered rubber/clay nanocmposites [J]. Maeromol., 2005, 38: 4551- 4553.

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