摘要
由１－硝基蒽醌与甲酸钠作用生成１－甲氧基蒽醌，收率７５％。１．甲氧基蒽醌与苯乙炔基溴化镁在ＴＨＦ中回流２４ｈ，水解后的混合物不经分离直接与氯化亚锡的乙酸溶液反应３０ｍｉｎ，一步法合成了题示化合物，收率４６％。
1-Nitro-anthraquinone reacts with methanol and sodium to give 1 -methoxy- anthraquinone in 75 % yield, from which the bile compound is synthesized in a one-step route. Thus, 1 - methoxy - anthraquinone reacts with phenylethynyl magnesium bromide in THF under reflux for 24h, the mixture formed is hydrolyzed, then without separation, is treated with a solution of stannous chloride in acetic acid for 30min to give the tide compound with a yield of 46%.
出处
《精细化工》
EI
CAS
CSCD
北大核心
1999年第2期51-53,共3页
Fine Chemicals
基金
国家自然科学基金!(29676005)
关键词
甲氧基
苯乙炔基
蒽
染料
发光材料
peroxyoxalate chemiluminescence, 1 -methoxy-9, 10-bis(phenylethynyl) anthracence
