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合成磷酸酯皮革加脂剂的研究 被引量:10

Study on Synthetic Phosphated Fatliquoring Agent
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摘要 植物油与乙醇胺在氮气保护下于120~150℃下进行酰胺化反应3h,然后在45~80℃下以P2O5为磷酸化剂反应5h,合成磷酸酯,再以三乙醇胺为中和剂调pH6.0~8.0,最后在60~90℃下与氯化石蜡、高碳醇等混配成加脂剂。该加脂剂用后手感柔软,不油腻,白色革不泛黄。 Vegetable oil is, under nitrogen protection, reacted with ethanolamine at 120-150℃ for 3h, and amidated, then reacted with P 2O 5 as a phosphorylating agent for 5h to synthesize phosphate, followed by the adjustment of pH to 6 0-8.0 with triethanolamine as a neutralizing agent. The product is finally mixed with chlorinated paraffin, high_carbon alcohol, etc, at 60-90℃ to produce the title fatliquor. Leather fatliquoured with it has soft but no grasy hands, and no yellowing surface has been found for the white leathers, as well.
出处 《皮革化工》 1999年第2期21-23,27,共4页 Leather Chemicals
关键词 烷基醇酰胺 磷酸酯 加脂剂 皮革 alkyl alcohol amide phosphate synthesis fatliquor leather
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