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无溶剂条件下锰(Ⅲ)-席夫碱配合物催化过氧化氢氧化醇(英文) 被引量：2

Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(Ⅲ) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant
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摘要 Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylic acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn(Ⅲ) Schiff-base complex as a catalyst under solvent-free conditions.The oxidation of alcohols occurred at 50℃ to give the corresponding ketones or carboxylic acids with a yield higher than 60%. Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylic acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn（Ⅲ） Schiff-base complex as a catalyst under solvent-free conditions.The oxidation of alcohols occurred at 50℃ to give the corresponding ketones or carboxylic acids with a yield higher than 60%.
作者 Hamid GOLCHOUBIAN Seyyed Ebrahim BABAEI
机构地区 Department of Chemistry Departmant of Chemistry
出处 《催化学报》 SCIE EI CAS CSCD 北大核心 2010年第6期615-618,共4页
基金 Supported by the Islamic Azad University-Ghaemshahr branch of the Islamic Republic of Iran
关键词 酒精 氧化 氢过氧化物 Schiff 底建筑群 Mn (III ) 建筑群 酉同类 alcohol oxidation hydrogen peroxide Schiff-base complex Mn（Ⅲ） complex ketone
分类号 O643.32 [理学—物理化学]
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参考文献36

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同被引文献22

  • 1丁宗彪,连慧,王全瑞,陶凤岗.钨化合物催化过氧化氢氧化环己酮合成己二酸[J].有机化学,2004,24(3):319-321. 被引量：16
  • 2张敏,魏俊发,白银娟,高勇,吴亚,苗延青,史真.用双氧水绿色氧化环己酮合成己二酸的研究[J].有机化学,2006,26(2):207-210. 被引量：41
  • 3程美令,曹向前,王春兰,李红喜,郎建平.含dmpzm配体的锌和镉配合物的合成、结构及性质研究[J].无机化学学报,2006,22(7):1222-1226. 被引量：2
  • 4卓馨,潘兆瑞,王作为,李一志,郑和根.[Cd(HO-BDC)(phen)·H_2O]_n的合成和晶体结构研究[J].无机化学学报,2006,22(10):1847-1851. 被引量：4
  • 5Ou - Yang M, Huang X R, Zhang Y L, et al. Bis [ 2 - (2 - pyridylmethylene amino) benzenesulfonato - k 3 N, N, O ] cadmium ( II ) dehydrate [J]. Acta Cryst, 2008,64:1 461.
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  • 10Cai C X, Ou - Yang M, Zhao Z Y, et al. Bis [ 2 - (2 - pyridyl - methylene - amino) benzenesulfonato - k 3 N, N, O ] Zinc ( H ) dehydrate [ J ]. Acta Cryst, 2008,64:1 195.

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催化学报
2010年 第6期

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