摘要
合成了化合物反式－９，１０－二苄基－９，１０－二氢－９，１０－菲二醇，通过ｍ．ｐ．，ＩＲ，１ＨＮＭＲ对其进行了表征；并经过Ｘ－射线分析确定了其单晶结构，晶体属三斜晶系，空间群Ｐī，ａ＝８．０５８（２），ｂ＝９．７１５（２），ｃ＝１４．４３７（３），α＝１０９．５９（３），β＝９５．９６（２），γ＝９６．０３（２）°，Ｚ＝２，Ｖ＝１０４７．１（４）３．没有发现其包合物．从结构上分析了不呈现包结性能的原因．
The compound trans 9,10 dibenzyl 9,10 dihydro 9,10 penanthrenediol was synthesized and confirmed by means of m.p.,IR and 1HNMR.The Crystal structure of this compound was determined by Four Cycle XRD techniques.The crystal belongs to triclinic system,space group pī.The unit cell parameters are:a=8.058(2),b=9.715(2),c=14.437(3),α=109.59(3),β=95.96(2),γ=96.03(2)°.It's inclusion compounds have not been found.The reasons of do not form inclusion compounds with other organic small molecule was investigated by analysis of molecular structure.
出处
《辽宁师范大学学报（自然科学版）》
CAS
1999年第1期39-44,共6页
Journal of Liaoning Normal University:Natural Science Edition
基金
国家自然科学基金
关键词
X-射线衍射
晶体结构
包合物
二苄菲二醇
trans 9,10 dibenzyl 9,10 dihydro 9,10 penanthrenediol,four cycle XRD,crystal structure,inclusion compound
