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锂离子电池正极材料聚三苯胺的合成及性能

Synthesis and electrochemical properties of PTPAn cathode materials for Li-ion batteries
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摘要 采用氧化聚合的方式合成了锂离子电池正极材料PTPAn。通过XRD、FT-IR、C-V、恒电流充放与循环寿命等测试研究了PTPAn的产物结构以及电化学性能。研究表明,PTPAn作为锂离子电池正极材料有着良好的电化学性能,首次放电容量达到101.34mAh/g,并且循环性能良好。 Li-ion battery cathode material PTPAn was successfully synthesized via the oxidative polymerization method.The products were characterized by X-ray diffraction(XRD) FR-IR and cyclic volammetry(C-V) and constant-current charge-discharge experiment to study the PTPAn structure and electrochemical properties.Experimental results indicated that,as the cathode material for Li-ion battery,PTPAn had good electrochemical performance,its initial discharge specific capacity was of 101.34mAh/g,and its cyclic performance was good.
出处 《电池工业》 CAS 2010年第3期165-168,共4页 Chinese Battery Industry
基金 湖南省自然科学基金(No.09JJ6017)
关键词 锂离子电池 正极材料 聚三苯胺 电化学性能 Li-ion battery cathode material PTPAn electrochemical property
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参考文献3

  • 1Amine K,Liu J,Belharouak I,et al,Advanced cathode materials for high-power applications[J].J Power Sources,2005,146:111-115.
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  • 3Andreas Petr,Carita Kvarnstrom,Lothar Dunsch,et al.Electrochemical synthesis of electrcactive polytriphenylamine[J].Synthetic Metals,2000,108:245-247.

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