摘要
以二茂铁双二氨基脲腙和取代醛为原料,经取代反应合成了7个新型的1,1′-二取代二茂铁双二氨基硫脲腙席夫碱化合物,其结构经UV,1HNMR,IR和元素分析表征。电化学研究表明,部分化合物对Ag+和Zn2+有较好的电化学识别能力。
Seven new 1,1′-disubstituted-ferrocenyl-bisthiocarbazide Schiff base compounds were synthesized by the substitution reaction of ferrocenyl-bisthiocarbazide.The structures were characterized by UV,1H NMR,IR and elemental analysis.The electrochemical studies showed that some of them exhibited good electrochemical recognition to Ag+ and Zn2+.
出处
《合成化学》
CAS
CSCD
北大核心
2010年第4期429-432,445,共5页
Chinese Journal of Synthetic Chemistry
关键词
二茂铁
席夫碱
合成
电化学识别
ferrocene
Schiff base
synthesis
electrochemical recognition