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新型1,1′-二取代二茂铁双二氨基硫脲腙席夫碱化合物的合成及其对金属离子的电化学识别 被引量:4

Synthesis of Novel 1,1′-Disubstituted-ferrocenyl-bisthiocarbazide Schiff Base Compounds and Their Electrochemical Recognition to Metal Ions
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摘要 以二茂铁双二氨基脲腙和取代醛为原料,经取代反应合成了7个新型的1,1′-二取代二茂铁双二氨基硫脲腙席夫碱化合物,其结构经UV,1HNMR,IR和元素分析表征。电化学研究表明,部分化合物对Ag+和Zn2+有较好的电化学识别能力。 Seven new 1,1′-disubstituted-ferrocenyl-bisthiocarbazide Schiff base compounds were synthesized by the substitution reaction of ferrocenyl-bisthiocarbazide.The structures were characterized by UV,1H NMR,IR and elemental analysis.The electrochemical studies showed that some of them exhibited good electrochemical recognition to Ag+ and Zn2+.
机构地区 郑州大学化学系
出处 《合成化学》 CAS CSCD 北大核心 2010年第4期429-432,445,共5页 Chinese Journal of Synthetic Chemistry
关键词 二茂铁 席夫碱 合成 电化学识别 ferrocene Schiff base synthesis electrochemical recognition
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参考文献17

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