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二维配位聚合物[Pb(suc)_(0.5)(phen)_2]_(2n)·2nNO_3的水热合成及晶体结构 被引量：1

Hydrothermal Synthesis and Crystal Structure of Two-Dimensional Coordination Polymer [Pb(suc)_(0.5)(phen)_2]_(2n)·2nNO_3
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摘要 采用水热法合成了二维配位聚合物[Pb(suc)0.5(phen)2]2n.2nNO3(H2suc=丁二酸,phen=1,10-邻菲啰啉).对其进行了元素分析、红外光谱表征和X射线单晶衍射测定.该配合物属于三斜晶系,空间群P-1,晶胞参数a=9.0618(17),b=11.533(2),c=11.963(2),α=96.404(2),β=109.720(2),γ=100.842(2),°V=1135.0(3)3,C52H36Pb2N10O10,Mr=1375.29,Dc=2.012 g/cm3,μ(MoKα)=7.484 mm-1,F(000)=662,Z=1,R1=0.0248,wR2=0.0630. A two-dimensional coordination polymer[Pb（suc）0.5（phen）2]2n·2nNO3（H2suc = succinic acid,phen = 1,10-phenanthroline） has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum and single-crystal X-ray diffraction.The complex crystallizes belongs to triclinic system,space group P-1 with cell parameters a= 9.0618（17）,b = 11.533（2）,c = 11.963（2） ,α= 96.404（2）,β= 109.720（2）,γ = 100.842（2）°,V= 1135.0（3） 3,C52H36Pb2N10O10,Mr = 1375.29,Dc = 2.012 g/cm3,μ（MoKα） = 7.484 mm-1,F（000） = 662,Z= 1,R1= 0.0248,wR2 = 0.0630.
作者 牛艳玲 李秀梅 王志涛
机构地区 通化师范学院化学系
出处 《通化师范学院学报》 2010年第8期24-25,30,共3页 Journal of Tonghua Normal University
基金 吉林省教育厅科学技术研究项目资助(No.2009.272)
关键词 水热合成 配位聚合物 晶体结构 hydrothermal synthesis coordination polymer crystal structure
分类号 O723.6 [理学—晶体学]
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参考文献11

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同被引文献41

  • 1李秀梅.二维配位聚合物[Cd(nicotinate)_2(H_2O)]_n的水热合成、晶体结构及荧光性质[J].化学研究,2005,16(4):39-41. 被引量：2
  • 2隋爱香,徐兴玲,唐宗薰.一类新型的多孔材料——多孔配位聚合物[J].大学化学,2006,21(4):1-10. 被引量：5
  • 3邢丽,张复实,向军辉,杨镜奎.自组装技术及其研究进展[J].世界科技研究与发展,2007,29(3):39-44. 被引量：17
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通化师范学院学报
2010年 第8期

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