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槲皮素-TOPO(TX-100)-SDS体系荧光法测定镥、钇、钪、钆、镧 被引量:5

Fluorescence Determination of Lutetium(Ⅲ), Yttrium(Ⅲ),Lanthanum(Ⅲ),Scandium(Ⅲ) and Gadolinium(Ⅲ) with Quercetin TOPO(TX 100)SDS
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摘要 研究了Lu3+、Y3+、Sc3+、Gd3+、La3+等几种L*-L发光型稀土离子与槲皮素-TOPO(TX-100)-SDS组成体系的荧光特性、影响因素及分析应用。于最佳条件下,测定上述稀土离子的最低检测限可达0.01mg/L。探讨了TOPO(TX-100)-SDS对Ln-槲皮素二元体系的增敏机理。 The systems formed by Lu 3+ ,Y 3+ ,Sc 3+ ,Gd 3+ ,La 3+ which belong to L  L type luminescence and quercetin TOPO(TX 100) SDS organic system were studied in detail on the fluorescence characteristics,affecting factors and analytical application. Under the optimum conditions, the detection limits of these RE ions were down to 0.01 mg/L. The enhancement mechanism of Ln quercetin binary system by TOPO(TX 100) SDS was discussed. The determination of Lu 3+ in the heavy rare earth sample was carried out by using the standard addition method.
出处 《淮海工学院学报(自然科学版)》 CAS 1999年第2期35-38,共4页 Journal of Huaihai Institute of Technology:Natural Sciences Edition
基金 山东大学自然科学基金
关键词 稀土元素 槲皮素 TOPO 荧光分析 SDS Lanthanides quercetin TOPO fluorimetry L  L luminescence
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