期刊文献+

聚氨酯/环氧树脂互穿网络半硬泡沫的力学性能及吸能特性 被引量:7

Mechanical properties and energy absorption of semirigid PU/ER interpenetrating polymer networks foams
原文传递
导出
摘要 采用同步法制备了聚氨酯/环氧树脂互穿聚合物网络(IPN)半硬泡沫。通过压缩和拉伸试验研究了泡沫材料密度对力学性能的影响。研究表明,在所研究的密度范围内,泡沫的压缩模量和屈服强度均与密度成指数关系。泡沫的拉伸模量和断裂强度与密度也存在类似的关系。利用这些方程可以很好地预测泡沫力学性能随密度的变化关系。IPN泡沫兼有较好的韧性和较高的拉伸强度。相同形变下,相同密度IPN半硬泡沫拉伸过程的单位体积吸能大于压缩过程的单位体积吸能。 A series of semirigid interpenetrating polymer networks (IPN) foams, based on polyurethane (PU) and epoxy resin(ER), with different densities were prepared by a simultaneous polymerization technique. Compression and tension properties of these foams were measured. Over the range of densities examined, the compression moduli and yield stress of these IPN foams could be described by a power- law relationship with respect to density respectively. The tensile moduli and break strength of these foams were also found to exhibit the similar relationships with respect to density of the foams. Therefore, the change of mechanical properties along with the density of the foams could be well predicted using these models. Experimental results reveal that the IPN foams possess both better ductility and higher tensile strength, and the energy absorption in tension test is higher compared with that in compression test at the same strain.
出处 《复合材料学报》 EI CAS CSCD 北大核心 2010年第4期118-123,共6页 Acta Materiae Compositae Sinica
关键词 聚氨酯/环氧树脂互穿聚合物网络 半硬泡沫 力学性能 吸能 polyurethane/epoxy interpenetrating polymer network semirigid foam mechanical property energy absorption
  • 相关文献

参考文献12

  • 1Tu Z H, Shim V P W, Lim C T. Plastic deformation modes in rigid polyurethane foam under static loading [J]. International Journal of Solids and Structures, 2001, 38(50/51): 9267- 9279.
  • 2林玉亮,卢芳云,王晓燕,赵习金.低密度聚氨酯泡沫压缩行为实验研究[J].高压物理学报,2006,20(1):88-92. 被引量:32
  • 3Shen Y, Golnaraghi F, Plumtree A. Modelling compressive cyclic stress - strain behaviour of structural foam [ J ]. International Journal of Fatigue, 2001, 23(6) : 491-497.
  • 4刘元俊,冯永强,贺传兰,邓建国,冀克俭,张银生,孙思修.玻璃微珠增强硬质聚氨酯泡沫塑料的压缩性能及热稳定性[J].复合材料学报,2006,23(2):65-70. 被引量:33
  • 5Frisch K C, Klempner D, Frisch H L. Recent advances in polymer alloys and IPN technology [J]. Materials and Design, 1983, 4(4) : 821-827.
  • 6Zhang Y, Hourston D J. Rigid interpenetrating polymer network foams prepared from a rosin-based polyurethane and an epoxy resin [J]. Journal of Applied Polymer Science, 1998, 69(2) : 271-281.
  • 7Lee Y, Ku W, Tsou J, et al. Epoxy modified polyurethane rigid foams [J]. Polymer Science: Part A, 1991, 29(8): 1083-1088.
  • 8杨宇润,陈永林,张志平,王得宁,胡春圃.聚氨酯/环氧树脂互穿网络硬质泡沫塑料反应过程和微观结构[J].功能高分子学报,2003,16(2):159-165. 被引量:10
  • 9胡运立,邹传品,苏醒,陈荣虎,李亚男.聚氨酯/环氧树脂互穿网络聚合物硬质泡沫机械性能研究[J].聚氨酯工业,2006,21(6):18-21. 被引量:10
  • 10Whinnery L L, Neuschwanger C L, Goods S H. Mechanical properties of a structural polyurethane foam and the effect of particulate loading, SAND98 - 8549C [R]. Washington: USDOE Office of Energy Research, 1998.

二级参考文献58

  • 1卢子兴,王仁,黄筑平,韩铭宝,田常津,李怀祥.泡沫塑料力学性能研究综述[J].力学进展,1996,26(3):306-323. 被引量:51
  • 2李国忠.玻璃纤维增强硬质聚氨酯泡沫塑料的微观结构及破坏机理研究[J].复合材料学报,1996,13(2):17-21. 被引量:13
  • 3方禹声 朱吕民.聚氯醇泡沫塑料[M].北京:化学工业出版社,1987.421-434.
  • 4Frisch K C, Klempner D. Glass transitions of topologically interpenetrating polymer networks[J]. Polym Eng Sci, 1974,14(9) :645--650.
  • 5Frisch H L, Klempner D, Frlsch K C. Recent advances in interpenetrating polymer networks [J]. Polym Eng Sci, 1982,22(17) :1143--1152.
  • 6Frisch K C, Klempner D, Mukherjee. Stress-strain properties and thermal resistance of polyurethane-polyepoxide interpenetrating polymer networks[J]. J Appl Polym Sci, 1974, 18: 689--98.
  • 7Cassidy E D, Xiao H X, Frisch H L, et al. Two-component interpenetrating polymer networks from polyurethane and epoxies [J].J Elastomers Plastics, 1984 ,16 : 84-- 92.
  • 8Hsieh K H, Han J L. Graft interpenetrating polymer networks of polyurethanes and epoxy T , Mechanical behaviour [J]. J Polym Sci: PartB, 1990,28 : 623-- 630.
  • 9Hsieh K H, Han J L. Graft interpenetrating polymer networks of polyurethanes and epoxy II , Toughening mechanism [J]. J Polym Sci:PartB, 1990,28 : 783-- 794.
  • 10Hsieh K H, Chiang Y C, Chern Y C, et al. Interpenetrating polymer networks of polyurethanes and epoxy resin I [J]. Die Angew Makromolekulare Chemie, 1991, 193: 89--98.

共引文献107

同被引文献55

引证文献7

二级引证文献38

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部