摘要
以SiO2为包裹相,Fe2O3为发色剂,采用固相法制备了硅铁红陶瓷颜料。考察了SiO2/Fe2O3质量比、铁源、煅烧温度、矿化剂以及助色剂等对色料的影响。采用XRD仪、扫描电镜和色度测量仪等分析手段对色料进行了表征。结果表明:SiO2/Fe2O3=85/15(质量比)时色料红度值最大,煅烧温度1100℃最佳,以硝酸铁制备的色料红度值达到22.31,以加入3%的复合矿化剂Na2SiF6:LiF=2∶1(质量比)效果最好,不同的助色剂对色料的影响不同,其中以La(NO3)3为助色剂的效果最好。
Silicon-iron-peach ceramic pigment was fabricated by solid-phase method,using SiO2 and Fe2O3 as raw materials.The influence of SiO2/Fe2O3 mass ratio,Fe2O3 sources,calcining temperatures,mineralizers and coloring aids on the color of the obtained pigments were systematically investigated.The as-prepared samples were characterized by XRD,colorimeter and SEM.Experimental results show that the red a-value is 12.51,when the SiO2:Fe2O3(mass ratio) was 85:15.The optimum firing temperature was 1100℃.The red a-value is 22.31 with Fe(NO3)3.9H2O as the source of Fe2O3.The mixture of Na2SiF6 and LiF to the mass ratio of 2:1 is the most effective mineralizer.La(NO3)3 is more beneficial to improving the red a-value of the pigments.
出处
《陶瓷学报》
CAS
北大核心
2010年第3期475-479,共5页
Journal of Ceramics
关键词
固相法
硅铁红
陶瓷色料
solid-phase method
silicon-iron-peach
ceramic pigment