摘要
研究了聚甲基丙烯酸甲酯(PMMA)在纳米氧化铝表面的吸附行为,采用透射红外光谱研究了吸附的PMMA中的羰基和纳米氧化铝表面羟基之间的氢键作用.结果表明,PMMA在纳米氧化铝表面的吸附曲线为典型的Langmuir曲线,饱和吸附值为1.2mg/m2,受氢键作用影响,键合羰基在红外光谱中的吸收峰向低波数方向移动.根据计算,羰基的最大键合值(即含键合羰基的甲基丙烯酸甲酯单元的总质量)为0.36mg/m2,其余为自由羰基.随着吸附量的增加,羰基的键合比例逐渐降低.吸附达到饱和时,羰基键合比例为0.30,说明PMMA主要以平铺的方式覆盖在纳米氧化铝的表面.
The adsorption behavior of poly（methyl methacrylate）（PMMA） on the surface of alumina nanoparticles was studied,the amount of adsorbed PMMA was examined with thermal gravimetric analysis（TGA） and the fraction of bound carbonyls of adsorbed PMMA was determined using transmission Fourier transform infrared spectroscopy（FTIR）.The adsorption curve has the form of Langmuir＇s isotherms.The carbonyl-stretching band of bound carbonyls shifts to lower wavenumbers because of the hydrogen bonding with aluminol groups.Curve fitting of the carbonyl-stretching region allowed the estimation of both the relative amounts and also the relative ratio of the absorption coefficients for the free and bound carbonyls.The fraction of bound carbonyls is 0.3 at the maximum adsorption,indicating that PMMA adsorbed on nano-alumina is arranged in a flat fashion.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2010年第10期2093-2097,共5页
Chemical Journal of Chinese Universities
关键词
纳米氧化铝
聚甲基丙烯酸甲酯
吸附
键合羰基
Alumina nanoparticle
Poly（methyl methacrylate）
Adsorption
Bound carbonyl
