期刊文献+

新型类Fenton催化剂用于酸性红B染料废水处理的研究 被引量:15

Treatment of Acid Red B wastewater by a novel Fenton-like catalyst
原文传递
导出
摘要 为了解决Fenton试剂反应前后需要调节pH值、催化剂不能重复利用的问题,本实验以酸性红B溶液作为模拟染料废水,探索以硫铁矿烧渣作为非均相催化剂进行类Fenton反应的催化活性,研究了H2O2投加量、催化剂投加量、pH值、反应时间对酸性红B去除效果的影响。在双氧水(H2O2质量分数为30%)投加量为30 mL/L、催化剂投加量为30 g/L、pH值在1~11范围内,反应4 h,浓度为200 mg/L的酸性红B去除率均达到95%以上,且反应后pH值在中性范围。实验结果表明,该非均相类Fenton反应体系对pH的适用范围广,且催化剂易于沉淀分离,反应数次后依然保持较高催化活性,能重复利用。 Using the traditional Fenton reagent,the pH values have to be adjusted and the catalyst can't be reused.In order to resolve these problems,the catalytic efficiency of pyrite cinder which is used to promote heterogeneous Fenton-like reaction was examined by employing Acid Red B as a model compound.The influencing factors were discussed,such as the dosage of hydrogen peroxide and pyrite cinder,reaction time,and initial pH value.When the dosage of H2O2 and pyrite cinder were 30 mL/L and 30 g/L,respectively,and initial pH value was in the range of 1 to 11,the removal rate of Acid Red B whose initial concentration was 200 mg/L was over 95% within 4 h,and pH changed to neutral.The result of the research indicated that pyrite cinder was active over a broad pH range,moreover,the catalyst could be separated by precipitation easily and retained its activity in repeated catalytic cycles.
出处 《环境工程学报》 CAS CSCD 北大核心 2010年第11期2413-2418,共6页 Chinese Journal of Environmental Engineering
基金 国家自然科学基金资助项目(50808136) 教育部科技重点项目(108142) 上海科委资助项目(08DZ2201600)
关键词 类FENTON 非均相催化 硫铁矿烧渣 酸性红B Fenton-like heterogeneous catalysis pyrite cinder Acid Red B
  • 相关文献

参考文献9

  • 1WangZ. H. , MaW. H. , ChenC. C. , etal. Light-assisted decomposition of dyes over iron-bearing soil clays in the presence of H2O2. Journal of Hazardous Materials, 2009, 168(2 -3) : 1246 - 1252.
  • 2Pera-Titus M. , Garcia-Molina V. , Banos M. A. , et al. Degradation of chlorophenols by means of advanced oxidation processes: A general review. Applied Catalysis B-Environmental, 2004, 47(4) : 219-256.
  • 3Lim C. L. , Morad N. , TengT. T. , etal. Treatment of terasil Red R Dye wastewater using H2O2/pyridine /Cu (II) system. Journal of Hazardous Materials, 2009, 168 (1) : 383-389.
  • 4Baldrian P. , Merhautova V. , Gabriel J. , et al. Decolorization of synthetic dyes by hydrogen peroxide with heterogeneous catalysis by mixed iron oxides. Applied Catalysis B-Environmental, 2006,66 ( 3 - 4) : 258 - 264.
  • 5陶长元,丁小红,刘作华,杜军,刘仁龙.Fenton类氧化技术处理有机废水的研究进展[J].化学研究与应用,2007,19(11):1177-1180. 被引量:39
  • 6Xue X. F. , Hanna K. , Deng N. S. Fenton-like oxidation of Rhodamine B in the presence of two types of iron (II, III) oxide. Journal of Hazardous Materials, 2009, 166(1) :407-414.
  • 7燕启社,孙红文,周长波,徐晓阳.类Fenton氧化在污染土壤修复中的应用[J].生态环境,2008,17(1):216-220. 被引量:30
  • 8Lin S. S. , Gurol M. D. Catalytic decomposition of hydrogen peroxide on iron oxide:Kinetics, mechanism, and implications. Environ. Sci. Technol. , 1998, 32(10) : 1417 - 1423.
  • 9Matta R. , Hanna K. , 6-trinitrotoluene in the minerals at neutral pH Kone T. ,et al. Oxidation of 2,4, presence of different iron-bearing Chemical Engineering Journal, 2008, 144(3) :453-458.

二级参考文献44

共引文献63

同被引文献161

引证文献15

二级引证文献82

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部