摘要
通过对相应呋喃糖进行Ｇｒｉｇｎａｒｄ亲和加成合成了苯基及苄基取代呋喃糖．所得主要产物的结构和绝对构型通过二维核磁共振进行了研究．其结果通过计算机分子模拟优化，并进行了比较和确认．
Phenyl and benzyl furanoses have been prepared stereoselectively by Grignard nucleophilic addition to their correspondent furanoses. Their structures and absolute configurations were studied and described by measuring the two dimensional NMR spectroscopy. The results have been compared and confirmed by computational optimizing model data.
出处
《波谱学杂志》
CAS
CSCD
北大核心
1999年第3期218-224,共7页
Chinese Journal of Magnetic Resonance
关键词
呋喃糖
亲和加成
绝对构型
二维
核磁共振
Grignard nucleophilic addition, Absolute configuration, 2D NMR spectroscopy, Computational optimizing
