期刊文献+

过氧化氢水溶液增湿Ca(OH)_2脱硫脱硝的实验研究 被引量:14

Experimental Investigation on the Flue Gas Desulfurization and Denitrification of Ca(OH)_2 Humidified by Hydrogen Peroxide Solution
下载PDF
导出
摘要 在小型喷雾气流反应脱硫脱硝实验台上研究了过氧化氢水溶液浓度以及各种因素(Ca/S摩尔比、Ca/N摩尔比、喷水量)对脱硫、脱硝效率的影响。结果表明,采用过氧化氢水溶液增湿Ca(OH)_2脱硫时,其脱硫效率随着过氧化氢水溶液浓度的增加而有较大的提高,提高幅度达15%~20%。单独脱硝和同时脱硫脱硝实验表明,采用过氧化氢水溶液增湿Ca(OH)_2脱硫效率有明显的提高,而过氧化氢溶液增湿Ca(OH)_2脱硝的效果并不明显,脱硝效率为5%左右。 In order to enhance SO2 and NO absorption rate and the removal efficiency, hydrogen peroxide as a strong oxidant was added in the semi--dry flue gas desulfurization and denitrification process. The effects of hydrogen peroxide solution concentrat (N) molar ratio and spray water flow rate on the removal efficiency were investig laboratory scale spray reactor. The results show that the S()2 removal efficiency 15 % to 20% with the increasing concentration of hydrogen peroxide solution when ion, Ca/S ated on a increases hydrogen peroxide solution is sprayed tO humidify Ca(OH)2 particles. The further investigation on the flue gas denitrification and simultaneous removal of SO2 and NO show that NO removal efficiency is not obvious which is about 5% when hydrogen peroxide solution is sprayed to humidify Ca(OH)2 particle, but the SO2 removal efficiency increases significantly.
出处 《锅炉技术》 北大核心 2010年第6期75-78,共4页 Boiler Technology
基金 国家自然科学基金资助项目(50606023)
关键词 半干法烟气脱硫 烟气脱硝 过氧化氢溶液 增湿 脱除效率 semidry flue gas desulfurization flue gas denitrification hydrogen peroxide solution humidification removal efficiency
  • 相关文献

参考文献9

  • 1C.L.Yang,H.Shaw.Aqueous absorption of nitric oxide induced by sodium chlorite oxidation in the presence of sulfur dioxide.Environ.Prog.,1998,17(2):80-85.
  • 2H.Chu,T.W.Chien,S.Y.Li.Simultaneous absorption of SO2 and NO from flue gas with KMnO4/NaOH solutions,Sci.Total Environ,2001,275:127-135.
  • 3Deo P.V.The use of hydrogen peroxide for the control of air pollution[J].Chem.Prot.Environ.,Study Environ.Sci.,1988,34:275-292.
  • 4Thomas D.,Coll E.S.,Vand Erschuren J.Kinetics of SO2 absorption into fairly concentrated sulphuric acid solutions containing hydrogen peroxide[J].Chem Eng Process,2003,42 (6):487-494.
  • 5Wang J.Advances in sp ray drying desulfurization for high sulfur coals[D].Cincinnati:University of C incinnati,1995.
  • 6柳瑶斌,周月桂,彭军,章明川.半干法烟气脱硫中过氧化氢溶液强化吸收二氧化硫的研究[J].燃料化学学报,2008,36(4):474-477. 被引量:7
  • 7J.L.Paiva,G.C.Kachan.Modeling,Simulation of a packed column for NOx absorption with hydrogen peroxide.Eng.Chem,1998,37:609-614.
  • 8E.B.Myers,T,J.,Overcamp.Hydrogen peroxide scrubber for the control of nitrogen oxides,Environ.Eng.Sci.,2002,9:321-327.
  • 9Nick D.Hutson,Renata Krzyzynska.Simultaneous Removal of SO2,NO.and Hg from Coal Flue Gas Using a NaClO2-Enhanced Wet Scrubber[J].Eng.Chem.Res.,2008,47.5825-5831.

二级参考文献8

  • 1王雷,章明川,黄颖,谢广录,周月桂,田凤国.氢氧化钙浆液脱硫反应及其干燥特性[J].上海交通大学学报,2005,39(8):1209-1213. 被引量:1
  • 2DEO P V. The use of hydrogen peroxide for the control of air pollution [ J ]. Chem Prot Environ, Stud Environ Sci, 1988, 34:275 -292.
  • 3THOMAS D, COLLE S, VANDERSCHUREN J. Kinetics of SO2 absorption into fairly concentrated sulphuric acid solutions containing hydrogen peroxide[ J ]. Chem Eng Process, 2003, 42 (6) : 487-494.
  • 4THOMAS D, VANDERSCHUREN J. The Absorption-oxidation of NOx absorption with hydrogen peroxide for the treatment of tail gases [ J ]. Chem Eng Sci, 1996, 51( 11 ) : 2649-2654.
  • 5WANG J. Advances in spray drying desulfurization for high sulfur coals[ D]. Cincinnati: University of Cincinnati, 1995.
  • 6HILL F F, ZANK J. Flue gas desulphurization by spray dry absorption[J]. Chem Eng Process, 2000, 39( 1 ) : 45-52.
  • 7郭彦霞,刘振宇,李允梅,刘清雅.氨再生条件对V_2O_5/AC同时脱硫脱硝活性的影响[J].燃料化学学报,2007,35(3):344-348. 被引量:22
  • 8梅欢,王祖武,董雪峰,吴浪.半干法喷射烟气脱硫试验研究[J].环境科学与技术,2003,26(1):19-20. 被引量:2

共引文献6

同被引文献194

引证文献14

二级引证文献66

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部