摘要
运用热力学理论和溶液理论，在不受经验性假设限制的条件下，分析了Polanyi吸附势的热力学含义，推导出固液界面吸附的基本条件、凝聚吸附条件、混合溶液竞争凝聚吸附以及顶替吸附的基本条件，并得出与Polanyi吸附势理论及其在溶液中吸附的应用相一致的结果。
Based on thermodynamics and solution theory,this paper analyzes the thermodynamics meaning of Polanyi adsorption Potential without the limitation of experiential suppose, educes the postulate of adsorption on solidityliquid interface, the condition of agglomerate adsorption, the postulate of competitive agglomerate adsorption in the mixed solutinn and substitute adsorption. The result is accordant to Polanyi enlarges the applied range of this theory and will conduce to lucubration on solution adsorption theory,
出处
《山东建材学院学报》
1999年第2期105-108,111,共5页
Journal of Shandong Institute of Building Materials
关键词
吸附
吸附垫
固-液吸附
热力学
adsorption
adsorption potential
solid-liquid adsorption
