摘要
将水性聚氨酯乳液与硅溶胶共混,制备了水性聚氨酯/硅溶胶复合乳液。采用TEM、激光粒度分析仪、流变仪、ATR-FTIR、TG对复合乳液及其涂膜进行表征,探讨了硅溶胶用量对复合涂膜性能的影响。ATR-FTIR分析表明,聚氨酯分子和硅溶胶之间可以形成氢键,但不存在化学键结合;TEM、激光粒度分析测试表明,硅溶胶质量分数的增加,使复合乳液粒子粒径增大,粒度分布变宽,当硅溶胶质量分数>20%后,乳胶粒子间易发生团聚;流变分析发现,加入硅溶胶后,乳液的表观黏度(ηa)增大,假塑性增强。性能测试结果表明,硅溶胶质量分数<20%时,复合乳液具有好的储存稳定性,复合涂膜表现出很好的热稳定性,48 h吸水率仅为18.94%,同时表现出很好的耐溶剂性能,拉伸强度达到28.98 MPa,铅笔硬度达2H,附着力0级。
Hybrid emulsions containing inorganic nanoparticles were prepared by blending waterborne polyurethane（WPU） emulsions with colloidal silica.The hybrid emulsion and its film were characterized by TEM,laser particle analyzer,rheometer,ATR-FTIR and TG respectively.The effects of silica content on the properties of the film were investigated.The ATR-FTIR test results confirm that there is no chemical bond formation between silica particle and urethane polymer chains except for hydrogen bonding.TEM and laser particle analyzer examinations show that the average particle size of the hybrid emulsions increases and the particle size distribution becomes wider with the increasing content of colloidal silica.The aggregation of particles in the hybrid emulsion would happen in the case of w（SiO2）20%.The rheological analysis reveals that the apparent viscosity（ηa） and the pseudoplasticity of the hybrids are increased with increasing silica content.The property tests indicate that below 20% silica content,the stability of the hybrid emulsion is good,and the thermal stability of its films shows much better,its water absorption is only 18.94%（after 48 h） also with the higher performance in the solvent resistance,tensile strength increases to 28.98 MPa,pencil hardness is 2H,adhesion is 0 grade.
出处
《精细化工》
EI
CAS
CSCD
北大核心
2010年第12期1161-1165,1223,共6页
Fine Chemicals
基金
国家自然科学基金项目(20876093
50973057)
陕西省13115重点项目(2007E118)
陕西科技大学研究生创新基金资助~~
关键词
水性聚氨酯
硅溶胶
有机-无机复合涂料
流变性能
涂膜性能
功能材料
waterborne polyurethane
colloidal silica
organic-inorganic hybrid coatings
rheological behavior
film property
functional materials
