期刊文献+

Synthesis and Crystal Structure of a Cobalt(Ⅱ) Complex with 2-(4'-Chlorine-benzoyl)-benzoic Acid and 1,10-Phenanthroline 被引量:2

Synthesis and Crystal Structure of a Cobalt(Ⅱ) Complex with 2-(4'-Chlorine-benzoyl)-benzoic Acid and 1,10-Phenanthroline
下载PDF
导出
摘要 A new metal-organic complex Co2(cbba)4(phen)2(μ2-OH2)(H2cbba=2-(4'-chlorine-benzoyl)benzoic acid,phen=1,10-phenanthroline) 1 has been hydrothermally synthesized and struc-turally characterized by single-crystal X-ray diffraction,elemental analyses,TG and IR spectroscopy.The compound crystallizes in triclinic,space group P1 with a=10.7659(7),b=17.1856(11),c=19.2022(13),α=83.8120(10),β=84.9930(10),γ=87.2070(10)°,V=3515.8(4)3,C80H50Cl4Co2N4O13,Mr=1534.90,Dc=1.450 g/cm3,μ(MoKα)=0.693 mm-1,F(000)=1568,Z=2,the final R=0.0490 and wR=0.1092 for 8216 observed reflections(Ⅰ 〉2σ(Ⅰ)).In the crystal structure,the cobalt atom is six-coordinated with three carboxylate oxygen atoms from three different cbba ligands,one oxygen atom from coordinated water molecule and two nitrogen atoms from phen ligand,showing a distorted octahedral geometry.Furthermore,it exhibits a 3D supramolecular network through π-π and hydrogen bonding interactions. A new metal-organic complex Co2(cbba)4(phen)2(μ2-OH2)(H2cbba=2-(4'-chlorine-benzoyl)benzoic acid,phen=1,10-phenanthroline) 1 has been hydrothermally synthesized and struc-turally characterized by single-crystal X-ray diffraction,elemental analyses,TG and IR spectroscopy.The compound crystallizes in triclinic,space group P1 with a=10.7659(7),b=17.1856(11),c=19.2022(13),α=83.8120(10),β=84.9930(10),γ=87.2070(10)°,V=3515.8(4)3,C80H50Cl4Co2N4O13,Mr=1534.90,Dc=1.450 g/cm3,μ(MoKα)=0.693 mm-1,F(000)=1568,Z=2,the final R=0.0490 and wR=0.1092 for 8216 observed reflections(Ⅰ 〉2σ(Ⅰ)).In the crystal structure,the cobalt atom is six-coordinated with three carboxylate oxygen atoms from three different cbba ligands,one oxygen atom from coordinated water molecule and two nitrogen atoms from phen ligand,showing a distorted octahedral geometry.Furthermore,it exhibits a 3D supramolecular network through π-π and hydrogen bonding interactions.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2010年第12期1814-1817,共4页 结构化学(英文)
基金 supported by the Science and Technology Research Projects of the Education Department of Jilin Province (No. 2009. 272)
关键词 hydrothermal synthesis crystal structure cobalt(Ⅱ) complex hydrothermal synthesis crystal structure cobalt(Ⅱ) complex
  • 相关文献

参考文献15

  • 1Lehn, J. M. Supramolecular Chemistry, Concepts and Perspectives. VCH, New York 1995.
  • 2Steed, J. W.; Atwood, J. L. Supramolecular Chemistry, Wiley and Sons, New York 2000.
  • 3Holliday, B. J.; Mirkin, C. A. Angew. Chem., Int. Ed. 2001, 40, 2022-2043.
  • 4Moulton, B.; Zaworotko, M. J. Chem. Rev. 2001, 101, 1629-1658.
  • 5Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34, 319-330.
  • 6Leininger, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853-908.
  • 7Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., lnt. Ed. 1999, 38, 2638-2684.
  • 8Blake, A. J.; Champness, N. R.; Hubberstey, E; Li, W. S.; Withersby, M. A.; Schro"der, M. Coord. Chem. Rev. 1999, 99, 117-183.
  • 9Wang, Q. W.; Li, X. M.; Meng, Q. L.; Liu, B.; Gao, G. G ChineseJ. Struct. Chem. 2009, 28, 335-337.
  • 10Sheldrick, G. M. SHELXS 97, Program for the Solution of Crystal Structure, University of G0ttingen, Germany 1997.

同被引文献5

引证文献2

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部