摘要
采用完全对角化方法，研究了３ｄ３ 态离子２ Ｅ 态能级分裂；在此基础上，用本文建立的中间场能量矩阵，对２ Ｅ态分裂的三阶微扰解析式 Ｄ（２ Ｅ） 进行了验证。结果表明：微扰解析式的结果远偏离对角化全组态的计算结果。
The splitting of the 2 E state for 3d 3 ions has been investigated in terms of the method of the diagonalization Hamiltonian matrices.On the basis of the analysical perturbation expression D( ２E) for the splitting of 2 E state is examined with the use of energy matrices.The results show that the perturbation expression for D( 2E) turns out results quite different from those obtained by the diagonal energy matrices.\;
出处
《宝鸡文理学院学报（自然科学版）》
CAS
1999年第3期43-46,共4页
Journal of Baoji University of Arts and Sciences(Natural Science Edition)
基金
陕西省教委专项基金
陕西省自然科学基金
关键词
3d^3离子
^2E态
三角晶场
掺杂晶体
双重谱线
d 3 inos
2 E state
perturbation expression
diagonalizing3d 3 inos
2 E state
perturbation expression
diagonalizing
