摘要
合成并表征了含2,6吡啶二羧酸根二茂钛基团的苯乙烯单体.通过含钛单体与苯乙烯的溶液共聚反应得到了稳定性高且可溶的共聚物.所得到的共聚物能溶于THF,CH2Cl2和甲苯中,其玻璃化转变温度为106℃.该含钛聚苯乙烯有望应用于惯性约束聚变(ICF)实验靶用聚合物微球的制备.
A styrenic monomer containing dicylopentadienyltitanium group and 2,6-pyridinedicarboxylate was synthesized and characterized.A stable and soluble copolymer was obtained by the solution copolymerization reaction between the titanium-containing monomer and styrene.This copolymer is soluble in THF,CH2Cl2 and toluene and exhibit a glass transition temperature of 106 ℃.This titanium-containing polystyrene could be used in the fabrication of the micro-spheres for the inertial confinement fusion(ICF) experiments.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2011年第1期196-200,共5页
Chemical Journal of Chinese Universities
基金
国家自然科学基金委员会-中国工程物理研究院联合基金(批准号:10676012)资助
关键词
钛
苯乙烯
共聚
Titanium
Styrene
Copolymerization