期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

TiCl3/PdCl2法活化多孔陶瓷基体制备透氢Pd膜

Fabrication of hydrogen-permeable palladium membranes on porous ceramic substrate activated by TiCl_3/PdCl_2 method
下载PDF
导出
摘要 以TiCl3取代SnCl2作为敏化剂,考察TiCl3/PdCl2活化法对Pd膜制备及性能的影响。所制备Pd膜的表面与断面形貌采用SEM与金相显微镜表征,测试膜的透氢性、选择性以及高温稳定性,比较了TiCl3/PdCl2与SnCl2/PdCl22种活化方法对Pd沉积速率的影响。结果表明:TiCl3/PdCl2活化法同样能够在多孔陶瓷基体表面形成活性催化层,并最终成功获得高性能的Pd膜。相对而言,TiCl3/PdCl2活化法更有利于Pd膜的快速形成,而且彻底避免了Sn对Pd膜的污染,有望成为SnCl2/PdCl2活化法的一种理想替代方法。 SnCl2 was replaced with TiCl3 as the sensitization agent,and the effects of the TiCl3/PdCl2 activation on the membrane fabrication and performance were investigated.The membrane surface and cross-section morphologies were characterized by SEM and metallographic microscope.The membrane permeability,selectivity and high-temperature stability were tested,and the influences of the TiCl3/PdCl2 and SnCl2/PdCl2 treatments on the palladium deposition were also studied.It could be concluded that the TiCl3/PdCl2 treatment successfully activated the porous ceramic surface as well and improved the membrane performances.Compared with the SnCl2/PdCl2 method,the TiCl3/PdCl2 treatment facilitated the membrane formation and the tin contamination to the membrane was avoided.The TiCl3/PdCl2 technique was an ideal alternative method to the SnCl2/PdCl2 method.
作者 王荣霞 俞健 宋军 张小亮 黄彦
机构地区 南京工业大学化学化工学院
出处 《南京工业大学学报（自然科学版）》 CAS 北大核心 2011年第1期38-43,共6页 Journal of Nanjing Tech University(Natural Science Edition)
基金 国家自然科学基金资助项目(20876075) 江苏省高校自然科学基金资助项目(09KJA530003)
关键词 PD膜 多孔陶瓷 化学镀 预活化 氢分离 palladium membrane porous ceramics electroless plating activation pretreatment hydrogen separation
分类号 O614.82 [理学—无机化学] TQ028.8 [化学工程]
  • 相关文献

参考文献10

  • 1Lukyanov B N, Andreev D V, Pannon V N. Catalytic reactors with hydrogen membrane separation [J]. Chem Eng J,2009,154( 1/ 2/3 ) :258 - 266.
  • 2Paglieri S N, Way J D. Innovation in palladium membrane research [ J ]. Sep Purif Methods,2002,31 ( 1 ) : 1 - 169.
  • 3Chen Yazhong,Wang Yuzhong, Xu Hengyong, et al. Efficient production of hydrogen from natural gas steam reforming in palladium membrane reactor [ J ]. Appl Catal B : Environ, 2008,81 ( 3/4 ) : 283 - 294.
  • 4Paglieri S N,Foo K Y,Way J D. A new preparation technique for Pal/alumina membranes with enhanced high-temperature stability [J]. Ind Eng Chem Res,1999,38(5) :1925 -1936.
  • 5Li Anwu, Xiong Guoxing, Gu Jinghua, et al. Preparation of Pd/ceramic composite membrane: 1. improvement of the conventional preparation technique [ J ]. J Membr Sci, 1996, 110 ( 2 ) : 257 - 260.
  • 6黄彦,范菁菁,舒世立,等.非金属基体化学镀的一种活化工艺:中国,ZL200710022996.6[P].2007-10-17.
  • 7Wu L Q, Xu N P, Shi J. Preparation of a palladium composite membrane by an improved electroless stability plating technique [ J]. Ind Eng Chem Res,2000,39:342 - 348.
  • 8邓超,张小亮,黄彦.多孔陶瓷基体表面的凝胶修饰及钯膜的制备[J].南京工业大学学报（自然科学版）,2010,32(1):92-97. 被引量：4
  • 9黄彦,胡小娟,陈卫东,等.一种适用于高温条件的管接头卡套:中国,ZL200810244136.1[P].2008-12-23.
  • 10Hu Xianjuan, Chen Weidong, Huang Yan. Direct modification of macroporous ceramics with pencil for fabrication of composite palladium membranes [ J ]. Int J Hydrogen Energy, 2010,35 ( 15 ) : 7803 - 7808.

二级参考文献10

  • 1Shu J, Grandiean B P A,Neste A V. Catalytic palladium-based membrane reactors : a review [J].Can J Chem Eng, 1991,69 : 1036 - 1060.
  • 2Paglieri S N, Way J D. Innovation in palladium membrane research[ J]. Sep Purif Methods ,2002,31 : 161 - 169.
  • 3Gryaznov V M ,Ermilova M M, Morozova L S, et al. Palladium alloys as hydrogen permeable catalysts in hydrogenation and dehydrogenation reactions [ J ]. J Less-Common Met, 1983,89:529 - 535.
  • 4Mardilovich I P, Engwall E, Ma Y H. Dependence of hydrogen flux on the pore size and plating surface topology of asymmetric Pd-porous stainless steel membranes [ J ]. Desalination, 2002, 144,85 - 89.
  • 5Huang Y, Dittmeyer R. Development of composite palladium membrane on sinter-metal support with ceramic barrier [ J ]. J Membr Sci ,2006,282:296 - 310.
  • 6Hu X J, Huaug Y, Shu S L, et al. Toward effective membrane for hydrogen separation: multichannel composite palladium membranes[J]. J Power Sources,2008,181 : 155 - 139.
  • 7Zhao H B, Pflanz K, Gu J H, et al. Preparation of palladium composite membranes by modified electroless plating procedure [ J ]. J Membr Sci, 1998,142:147 - 157.
  • 8徐恒泳,侯守福,李文钊,等.一种复合金属钯膜或合金钯膜及其制备方法:中国,ZL200410021025.6[P].2005-07-20.
  • 9Lide D R. CRC handbook of chemistry and physics [ M ]. Boca Raton : CRC Press ,2005.
  • 10俞健,胡小娟,黄彦.多孔不锈钢表面的陶瓷修饰及所负载的透氢钯膜[J].化学进展,2008,20(7):1208-1215. 被引量：4

共引文献4

南京工业大学学报（自然科学版）
2011年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部