期刊文献+

磺胺甲基异恶唑与铜离子的络合

Complexation between Sulfamethexazole and Cu^(2+)
下载PDF
导出
摘要 研究探讨了磺胺甲基异恶唑(SMX)与常见重金属离子Cu的络合情况,分析了SMX与Cu络合前后的紫外特征。结果表明,SMX与Cu发生了明显的络合,而且受到pH值的极大影响。这一现象可以用不同pH值下SMX的存在形态进行可靠解释,在pH值为8.0时,静电吸引对SMX与Cu络合的贡献非常大,SMX与Cu络合前后的紫外特征没有发生明显变化。 The complexation situations between sulfamethexazole(SMX) and common heavy metal ion Cu were discussed.The ultraviolet characteristics of SMX and Cu before and after complexation were analyzed.The results showed that the a significant complexation could be observed between SMX and Cu.pH value was greatly affected.This phenomenon could be well explained by different SMX species at different pHs.Electrostatic interaction was the most important interactions force between SMX and pH at pH value of 8.0.No significant changes were observed for SMX before and after complexation regarding its UV characteristics.
出处 《安徽农业科学》 CAS 北大核心 2010年第35期20253-20255,共3页 Journal of Anhui Agricultural Sciences
基金 云南省科技计划项目(2008CA002)
关键词 抗生素 磺胺甲基异恶唑 CU PH值 Antibiotics SMX Cu pH value
  • 相关文献

参考文献12

  • 1DAUGHTON C G,TERNES T A.Pharmaceuticals and personal care products in the environment:Agents of subtle change[J].Environmental Health Perspectives,1999,107:907-938.
  • 2SCHULSENER M P,BESTER K.Persistence of antibiotics such as macrolides,tiamulin and salinomycin in soil[J].Environmental Pollution,2006,143(3):565-571.
  • 3TERNES T A,KRECKEL P,MUELLER J.Behaviour and occurrence of estrogens in municipal sewage treatment plants-II.Aerobic batch experiments with activated sludge[J].Science of The Total Environment 1999,225(1/2):91-99.
  • 4胡洪营,王超,郭美婷.药品和个人护理用品(PPCPs)对环境的污染现状与研究进展[J].生态环境,2005,14(6):947-952. 被引量:87
  • 5ALPUCHE C,GARAU J,LIM V.Global and local variations in antimicrobial susceptibilities and resistance development in the major respiratory pathogens[J].International Journal of Antimicrobial Agents,2007,30:135-138.
  • 6BRAGA O,SMYTHE G A,SCHAFER A I,et al.Fate of steroid estrogens in Australian inland and coastal wastewater treatment plants[J].Environmental Science & Technology,2005,39,(9):3351-3358.
  • 7PENG X,TAN J,TANG C,et al.Multiresidue determination of fluoroquinolone,sulfonamide,trimethoprim,and chloramphenicol antibiotics in urban waters in China[J].Environmental Toxicology and Chemistry,2008,27:73-79.
  • 8CHANG H,HU J Y,SHAO B.Occurrence of natural and synthetic glucocorticoids in sewage treatment plants and receiving river waters[J].Environmental Science & Technology,2007,41(10):3462-3468.
  • 9XU W H,ZHANG G,LI X D,et al.Occurrence and elimination of antibiotics at four sewage treatment plants in the Pearl River Delta (PRD),South China[J].Water Research,2007,41(19):4526-4534.
  • 10PASTOR-NAVVARRO N,BRUN E M,GALLEGO-IGLESIAS E,et al.Development of immunoassays to determinate sulfamethoxazole residues in wastewaters[J].Journal of Environmental Monitoring 2009,11(5):1094-1100.

二级参考文献33

  • 1俞道进,曾振灵,陈杖榴.四环素类抗生素残留对水生态环境影响的研究进展[J].中国兽医学报,2004,24(5):515-517. 被引量:46
  • 2EPA.Pharmaceuticals & Personal Care Products in the Environment:An Emerging Concern?.http://www.epa.gov/nerl/research/1999/html/ g8-14.html.,1999-12-24/2005-3-20.
  • 3MARTA C,FRANCISCO O,JUAN M L,et al.Behavior of pharmaceuticals,cosmetics and hormones in a sewage treatment plant[J].Water Research,2004,38:2918-2926.
  • 4SNYDER SA,WESTERHOFFP,YOON Y,et al.Pharmaceuticals,personal care products,and endocrine disruptors in water:Implications for the water industry.Environment[J].Engineering Science,2003,20 (5):449-469.
  • 5TERNES TA,MEISENHEIMER M,MCDOWELL D.Removal of pharmaceuticals during drinking water treatment[J].Environmental Science & Technology,2002,36:3855-3863.
  • 6GLEN R B,JORDAN M P,ZHANG SH Y,et al.Pharmaceuticals and personal care products (PPCPs) and endocrine disrupting chemicals (EDCs) in stormwater canals and Bayou St.John in New Orleans,Louisiana,USA[J].The Science of the Total Environment,2004,333:137-148.
  • 7TILL L,DAVID E.Nitromusk and polycyclic musk compounds as long-term inhibitors of cellular xenobiotic defense systems mediated by multidrug transporters[J].Environmental Health Perspectives,2005,13(1):17-24.
  • 8STEGER-HARTMANN T,LANGE R,SCHWEINFURTH H.Environmental risk assessment for the widely used iodinated X-ray contrast agent iopromide (ultravist) [J].Ecotoxicology And Environmental Safety,1999,42:274-281.
  • 9SIMON D C,JOHN M,JOHN B.Ecosystem response to antibiotics entering the aquatic environment[J].Marine Pollution Bulletin,2005,51:218-223.
  • 10KUMMERER K,AL-AHMAD A,MERSCH-SUNDERMANN V.Biodegradability of some antibiotics,elimination of the genotoxicity and affection of wastewater bacteria in a simple test[J].Chemosphere,2000,40:701-710.

共引文献92

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部