摘要
在配住滴定中,当同时考虑金属离子的副反应时,如何推导pMep和pMsp两个计算公式,提出用金属离子浓度同标准─—游离态化法.
This paper tries to derive the calculation formulas of pMep and pMsp in compleximetry in theexistence of by - reaction of metalion. A new method is presented in which the concetration of metalion inindicator discoloration point and stoichimetry point are standardized according to its concentration in free statawith the help of constant of look - up table and distribution mefficient. This method make the calcucationformula and its derivation of two points vnited and it is convenient for the study and exchange of researches.
出处
《长沙大学学报》
1999年第2期94-95,共2页
Journal of Changsha University
关键词
滴定终点
化学计量点
游离态化法
配位滴定
metalion,free state, end point of titration, stoichiometry point