摘要
报道了在氢氧化钾的甲醇溶液中，碘氧化２，６＿ 二特丁基＿ ４＿ 甲酚生成稳定的苯氧基化合物Ⅰ，并对反应条件进行了研究。实际结果表明：碘氧化２，６＿ 二特丁基＿ ４＿ 甲酚合成Ⅰ，不仅操作简单，而且产率高达９０％ 以上。
In the paper,Oxidation of Phenols using iodine as an oxidating agent is described.The Oxidation of 2,6_di_tert_butyl_methylphenol with iodine to give a stable 4_(2,6_di_t_butyl_4_methylPhenol)_2,6_di_t_butyl_4_methyl_,5_Cyclohexadiene_l_one in methanol contain.The results shows that it is operated simply and production rate is highter 90 percent .such alkali as potassium hydroxide.While it is investigated in the Quantity of Oxidant,the Quantity of potassium hydroxide,time of reaction ,the Quantity of solvent etc.
出处
《华东地质学院学报》
1999年第3期260-264,共5页
Journal of East China Geological Institute
关键词
二特丁基
环已二烯
苯氧二聚体
甲酚
碘氧化
Oxidation,2,6-di-tert-buty-4-methylphenol 4-(2,6-di-t-butyl-4-methyl-Phenoxy)-2,6-di-t-butyl-4-methyl-2,5-Cyclohexadiene-l-one
