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High power nano-LiMn_2O_4 cathode materials with high-rate pulse discharge capability for lithium-ion batteries 被引量:1

High power nano-LiMn_2O_4 cathode materials with high-rate pulse discharge capability for lithium-ion batteries
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摘要 Nano-LiMn2O4 cathode materials with nano-sized particles are synthesized via a citric acid assisted sol-gel route. The structure, the morphology and the electrochemical properties of the nano-LiMn204 are investigated. Compared with the micro-sized LiMn2O4, the nano-LiMn2O4 possesses a high initial capacity (120 mAh/g) at a discharge rate of 0.2 C (29.6 mA/g). The nano-LiMn2O4 also has a good high-rate discharge capability, retaining 91% of its capacity at a discharge rate of 10 C and 73~ at a discharge rate of 40 C. In particular, the nano-LiMn2O4 shows an excellent high-rate pulse discharge capability. The cut-off voltage at the end of 50-ms pulse discharge with a discharge rate of 80 C is above 3.40 V, and the voltage returns to over 4.10 V after the pulse discharge. These results show that the prepared nano-LiMn2O4 could be a potential cathode material for the power sources with the capability to deliver very high-rate pulse currents. Nano-LiMn2O4 cathode materials with nano-sized particles are synthesized via a citric acid assisted sol-gel route. The structure, the morphology and the electrochemical properties of the nano-LiMn204 are investigated. Compared with the micro-sized LiMn2O4, the nano-LiMn2O4 possesses a high initial capacity (120 mAh/g) at a discharge rate of 0.2 C (29.6 mA/g). The nano-LiMn2O4 also has a good high-rate discharge capability, retaining 91% of its capacity at a discharge rate of 10 C and 73~ at a discharge rate of 40 C. In particular, the nano-LiMn2O4 shows an excellent high-rate pulse discharge capability. The cut-off voltage at the end of 50-ms pulse discharge with a discharge rate of 80 C is above 3.40 V, and the voltage returns to over 4.10 V after the pulse discharge. These results show that the prepared nano-LiMn2O4 could be a potential cathode material for the power sources with the capability to deliver very high-rate pulse currents.
出处 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第2期532-537,共6页 中国物理B(英文版)
基金 supported by the National Natural Science Foundation for Postdoctoral Scientists of China (Grant No. 20090451554)
关键词 lithium-ion batteries lithium manganese oxide high-rate pulse discharge lithium-ion batteries, lithium manganese oxide, high-rate, pulse discharge
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