摘要
用量子化学计算研究了碳正离子 １，２ 重排的氢、甲基迁移重排机理，结果表明其历程是一种正离子系统中的原子迁移的协同历程。
The rearrangement mechanism of 1.2 hydrogen or methyl in carbenium ions was studied by quantum chemical calculation.The calculated results showed that the mechanism was concerted reaction of the atom migration in carbenium ions.Hence,the point of view was on exact that the mechanism of anion migration is considered in ordinary organic theory.
出处
《河北师范大学学报（自然科学版）》
CAS
1999年第3期385-387,共3页
Journal of Hebei Normal University：Natural Science
