摘要
首先介绍了阳离子聚合的简史。由于阳离子高活性的特点使其发展较慢。阳离子聚合研究的突破来自对引发反应的深入理解，而近代阳离子聚合的要点则在于使链引发、链增长和链终止成为可控。阳离子聚合的进展密切与大分子工程相关。本文对活性阳离子聚合做了较详细的讨论。并例举遥爪聚合物及嵌段聚合物的研究成就。最后。
In this paper at first a very brief introduction of the history of carbocationic polymerization was given.The slow development in a period of the past 3040 years was attributed to its high reactivity.The breakthrough began with the clear understanding of the nature of initiation reaction and the essence of modern carbocationic polymerization was to bring the initiation,propagation and termination under control.The recent progress of carbocationic polymerization is in close connection with macromolecular engineering,especially by living carbocationic polymerization(LCCP).A few examples of macromolecular engineering by INIFER and LCCP were presented.Finally,the trend and problem met in this field are advanced.
出处
《高分子通报》
CAS
CSCD
1999年第3期88-93,共6页
Polymer Bulletin
关键词
阳离子聚合
活性阳离子聚合
可控聚合
Cationic polymerization, Living cationic Polymerization,Controled cationic polymerization
