期刊文献+

物理法制备炭陶复合吸附材料及其表征 被引量:4

Preparation and Characterization of Carbon /Pottery Composite with Physical Method
下载PDF
导出
摘要 以木炭和黏土为原料,采用物理法制备炭陶复合吸附材料,讨论温度和保温时间对其吸附性能的影响,采用扫描电镜(SEM)和全自动比表面积及孔径分析仪对其微观结构和孔径分布进行表征,提出原位活化的思路。结果表明:热处理过程中,木炭的收缩在木炭和陶土之间形成发达的孔隙;黏土在烧结之后并没堵塞活性炭的孔隙结构;块状炭陶的吸附性能比粉状的高;炭陶在制备过程中受原位活化作用。在较优的工艺条件下,炭陶复合吸附材料的亚甲基蓝吸附值和碘吸附值分别为127.5和543.6 mg·g-1。 The preparation of carbon /pottery composite from wood charcoal and clay was made with physical method and the effect of temperature and holding time on the adsorption capability of carbon /pottery composite was discussed in this paper.In addition,microstructure and pore distribution of carbon /pottery composite were characterized by SEM and BET and the idea of in situ activation was proposed.The results show the pore between wood charcoal and pottery developed during heating treatment while the clay did not block the pore structure of wood charcoal.On the other hand,the adsorption capability of lumpish shape was higher than pulverous shape.Furthermore,the activated reaction of carbon / pottery composite could be defined as in situ activation.Therefore,under optimized experimental condition,the adsorption values of methylene blue and iodine of carbon /pottery composite were 127.5 and 543.6 mg.g-1 respectively.
出处 《林业科学》 EI CAS CSCD 北大核心 2010年第12期125-129,共5页 Scientia Silvae Sinicae
基金 国家自然科学基金资助项目(30771682) 福建省自然科学基金计划资助项目(E0710002) 国家林业局南方山地用材林培育重点实验室共同资助
关键词 炭陶复合材料 孔径分布 原位活化 活性炭 carbon /pottery composite pore distribution in situ activation activated carbon
  • 相关文献

参考文献11

  • 1李湘洲.磷酸法制备棉秆活性炭的研究[J].林业科学,2005,41(5):115-117. 被引量:6
  • 2林冠烽,程捷,黄彪,杨建华,吴新华.高活性木炭的制备与孔结构表征[J].化工进展,2007,26(7):995-998. 被引量:17
  • 3林冠烽.炭化工艺对高活性木炭性能的影响[J].林业科学,2009,45(4):112-116. 被引量:11
  • 4钟连兵,刘利盟,叶枫,于杰.C_(sf)/BAS玻璃陶瓷复合材料的制备及其力学性能研究[J].材料科学与工艺,2008,16(4):445-448. 被引量:1
  • 5Arriagada R,García R,Molina-Sabio M,et al.1997.Effect of steam activation on the porosity and chemical nature of activated carbons from Eucalyptus globules and peach stones.Microporous Materials,8(3/4):123-130.
  • 6Hu Z,Srinivasan M P,Ni Y.2001.Novel activation process for preparing highly microporous and mesoporous activated carbons.Carbon,39(6):877-886.
  • 7Molina-Sabio M,Gonzalez J C,Rodríguez-Reinoso F.2004.Adsorption of NH3 and H2S on activated carbon and activated carbon-sepiolite pellets.Carbon,42(2):448-450.
  • 8Qian Q,Machidab M,Tatsumoto H.2007.Preparation of activated carbons from cattle-manure compost by zinc chloride activation.Bioresource Technology,98 (2):353-360.
  • 9Yates M,Blanco J,Avila P,et al.2000.Honeycomb monoliths of activated carbons for effluent gas purification.Microporous and Mesoporous Materials,37 (1/2):201-208.
  • 10Yates M,Blanco J,Martin-Luengo M A,et al.2003.Vapour adsorption capacity of controlled porosity honeycomb monoliths.Microporous and Mesoporous Materials,65 (2/3):219-231.

二级参考文献38

共引文献25

同被引文献23

引证文献4

二级引证文献11

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部