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AlCl_3-异丙醇络合催化剂催化1-癸烯齐聚反应的研究 被引量:5

STUDY ON THE 1-DECENE OLIGOMERICATION CATALYZED BY ALUMINUM CHLORIDE-ISOPROPANOL COMPLEX
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摘要 使用AlCl_3-异丙醇络合催化剂对1-癸烯齐聚反应进行研究,合成了高黏度聚α-烯烃合成润滑油(PAO)。考察了催化剂用量、反应温度、反应时间以及烯烃原料对PAO收率的影响。结果表明,在A1Cl_3摩尔分数为4%、异丙醇与AlCl_3摩尔比为0.3~0.7、反应温度20~60℃、反应时间4h的条件下,合成高黏度PAO的收率在90%以上,并且具有低凝点、高黏度指数的特点。 The oligomerization of 1-decenes was studied using aluminum chloride-isopropanol complex as catalyst,and high viscosity poly-alpha-olefins (PAO) were synthesized. The effects of reaction conditions, such as catalyst amount, molar ratio of isopropanol/AlCl3, reaction temperature, reaction time and various olefin feeds on the yield and property of PAO were investigated. The experimental results showed that under the conditions of an AlCl3 mole fraction of 4% ,an isopropanol/AlCl3 molar ratio in the range of 0.3-0.7, reaction temperature in the range of 20--60℃ and a reaction time of 4 h, the yield of high viscosity PAO could be more than 90%, and the product having low condensation point and high viscosity index.
出处 《石油炼制与化工》 CAS CSCD 北大核心 2011年第4期67-69,共3页 Petroleum Processing and Petrochemicals
基金 辽宁省教育厅资助项目(20060506)
关键词 聚Α-烯烃 齐聚 氯化铝-异丙醇络合物 1-癸烯 高黏度 poly-alpha-olefins oligomerization aluminum chloride-isopropanol complex 1-decene high viscosity
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