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汽车散热器新型铝合金钎焊接头腐蚀行为的分析 被引量:10

Research on corrosion of automobile condenser brazed with novel aluminium alloys
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摘要 采用微区电化学测试和浸泡试验法研究了采用自行新研制的汽车散热器用新型铝合金管(Minicore)钎焊接头分别在0.1mol/L(pH=6)和0.6mol/L NaCl(pH=3)溶液中的腐蚀行为.文中采用微区电化学测试和浸泡试验法对母材、钎焊缝及腐蚀形貌的显微组织进行了分析,焊接使用在保护气氛下钎焊,钎料为Al-si合金(AA4343).结果表明,新型Minicore铝合金管比钎缝区域的点蚀电位高.扫描电镜(SEM)结果表明,临近钎缝的铝合金管未发生晶间腐蚀,而钎缝区域(20-30μm)呈现品间腐蚀,晶间腐蚀由钎缝A1-Si共晶组织中的铝基体发生了优先溶解,留下了富硅的合金相. The corrosion behaviour of automobile condenser brazed with novel aluminium alloys have been studied in 0.1 mol/l NaCl(pH=6) and 0.6 mol/l NaCl(pH=3) solutions by microelectrochemical measurements and immersion test.The microstructure of the fin materials,tube alloys and brazing region and corrosion morphology have been investigated by SEM.The controlled atmosphere brazing(CAB) was used and Al-Si alloys was used for clad alloys for aluminium brazing sheet.The results indicate tube region shows less susceptibility to corrosion attack than the brazed region.The SEM results show that the tube region has no intergranular corrosion and the thickness of the brazed region is about 20-30 μm.The brazed region shows intergranular corrosion,but it is corrosion of the eutectic of Al-Si with α-aluminium is preferential dissolution and Si-rich intermetallic particles remains.
出处 《焊接学报》 EI CAS CSCD 北大核心 2011年第6期25-28,114,共4页 Transactions of The China Welding Institution
基金 国家自然科学基金资助项目(50975052)
关键词 保护气氛钎焊 汽车散热器 显微组织 腐蚀性 controlled atmosphere brazing condenser microstructure corrosion
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参考文献6

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同被引文献78

  • 1刘恒三,毛卫民,陈冷,冯惠平.退火方式对深冲压钢板晶粒尺寸不均匀性的影响[J].北京科技大学学报,2004,26(4):377-381. 被引量:5
  • 2王祝堂.汽车热交换器用铝板带箔[J].轻合金加工技术,2005,33(11):1-8. 被引量:15
  • 3张新明,吴文祥,刘胜胆,蹇雄,唐建国.退火过程中AA3003铝合金的析出与再结晶[J].中南大学学报(自然科学版),2006,37(1):1-5. 被引量:27
  • 4张启运 刘淑祺 等.氟铝酸钾高温铝钎剂的湿法合成及其在钎焊时的作用机理[J].焊接学报,1982,3(4):153-157.
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  • 8Zhang G W, Bao Y F, Jiang Y F, et al. Mierostructure and mechanical properties of 6063 aluminum alloy brazed joints with Al- Si-Cu-Ni-RE filler metal [ J ]. Journal of Materials Engineering and Performance. 2011, 20(8): 1451-1456.
  • 9Wang S H, Zhou H P, Kang Y P. The influence of rare earth el- ements on microstructures and properties of 6061 aluminum alloy vacuum-brazed joints [ J ]. Journal of Alloys and Compounds, 2003, 352(1/2) : 79 -83.
  • 10Chang S Y, Tsao L C, Li T Y, et al. Joining 6061 aluminum alloy with Al-Si-Cu filler metals [ J ]. Journal of Alloys and Compounds, 2009, 488( 1 ) : 174 - 180.

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