期刊文献+

掺杂Co的纳米TiO_2光催化降解水中五氯苯酚的研究 被引量:2

Study on Photocatalytic Degradation of PCP by Using Nanopowders TiO_2 Doped with Co
下载PDF
导出
摘要 采用溶胶-凝胶法制备的掺杂Co纳米TiO_2粉体(Co/TiO_2),在紫外光照射下光催化降解水中五氯苯酚(PCP)。研究了光照反应时间、催化剂加入量、PCP溶液初始浓度等因素对纳米Co/TiO_2光催化降解五氯苯酚的影响。在溶液中五氯苯酚初始浓度为0.01mg/mL,pH=9~10,纳米Co/TiO_2加入量达到0.25mg/mL,光照时间为150min时,溶液中的PCP降解率达到了97%;纳米Co/TiO_2粉末与纳米TiO_2相比,在紫外光和可见光下对水中PCP的降解效果均有一定提高。 Under UV in:adiation, nanopowders TiO2 doped with Co which were prepared by sol - gel methods were used in the photocatalytic degradation of pentachlorophenol (PCP). The effects of degradation time, the amount of catalyst, and initial concentration on photoeatalytic degradation of PCP were investigated. The initial concentration of the PCP solution was 0.01 mg/mL, pH 9.0 - 10, the amount of catalyst was 0.25 mg/mL, when degradation time was 150 min, the results indicated that the degradation rates of PCP is over 97%. Under the UV and visible light, compared to pure TiO2 , nanopowders of Co/TiO2 have a certain increase for the photocatalytic degradation of PCP.
出处 《钛工业进展》 CAS 2011年第3期17-20,共4页 Titanium Industry Progress
基金 陕西省自然科学基金(2009JM2007) 西北工业大学基础研究基金(NPU-FFR-JC200823)
关键词 纳米TIO2 掺杂Co纳米Co/TiO2 光催化降解 五氯苯酚 nano TiO2 nano Co/TiO2 photo catalytic degradation pentachlorophenol
  • 相关文献

参考文献9

  • 1Hayes W J, Laws E R. Handbook of Pesticide Toxicology Classes of Pesticides [ M ]. New York: Academic Press, 1991 : 1206 - 1216.
  • 2Chen Yingxu, Chen Hualin, Xu Yuntai. Irreversible sorption of pentachlorophenol to sediments: experimental observations [J]. Environmental International. 2004, 30(1) : 31-37.
  • 3Grad)' C P L Jr. Biodegradation of toxic organics: status and potential[ J ]. Journal of Environmental Engineering, 1990, 116:805-828.
  • 4王宏,杨霓云,沈英娃,王波,王鲁昕.海河流域几种典型有机污染物环境安全性评价[J].环境科学研究,2003,16(6):35-36. 被引量:39
  • 5张兵,郑明辉,刘芃岩,包志成,徐晓白.五氯酚在洞庭湖环境介质中的分布[J].中国环境科学,2001,21(2):165-167. 被引量:82
  • 6罗进飞,于洪锋,李洪,李鑫钢.五氯苯酚光催化降解的影响因素分析[J].化工进展,2009,28(5):899-903. 被引量:2
  • 7Gunlazuardi J, Lindu W A. Photocatalytic degradation of pentachlorophenol in aqueous solution employing immobilized Ti02 supported on titanium metal [ J ]. Journal of Photochemistry and Photobiollgy, 2005, 173( 1 ) : 51-55.
  • 8Zhou L, Zhang S Y, Cheng J C, et al. Optical absorption of nanoscaled CoTiOa and NiTiO3 [ J ]. Materials Science and Engineering B, 1997, 49(2) : 117 - 122.
  • 9Iwasaki M, Hara M, Kawada H, el al. Cobalt ion -doped TiO2 photocatalyst response to visible light[J]. Journal of Colloid Interface Science, 2000, 224 ( 1 ) : 202-204.

二级参考文献30

共引文献116

同被引文献17

引证文献2

二级引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部