摘要
本文采用密闭压力容器试验（ＣＰＶＴ）测定有机过氧化物的热分解过程，得到压力（Ｐ）时间（ｔ）曲线和压力变化速度（ｄＰ／ｄｔ） 时间（ｔ）曲线，根据曲线确定其分解的最大压力ＰＭ 和最大压力变化速度（ｄＰ／ｄｔ）Ｍ 值．利用ＰＭ×（ｄＰ／ｄｔ）Ｍ 结果对化合物的热分解反应激烈程度进行分类，它与热爆炸容器试验（ＴＥＶＴ）结果有良好的相关性．
The process of heating decomposition of organic peroxides were measured by closed pressure vessel test(CPVT).In a closed vessel the decomposition was observed as a pressure rise characterized by a maximum rate of pressure rise (d P /d t ) M and a maximum pressure( P M). The violence of decomposition are classified with a pressure effect of P M×(d P /d t ) M,and have good interrelation between CPVT and literature of thermal explosion vessel test(TEVT).
出处
《广西大学学报（自然科学版）》
CAS
CSCD
1999年第4期271-273,共3页
Journal of Guangxi University（Natural Science Edition）
基金
教育部留学回国科研启动基金!(教外司留[1997]436号)
关键词
有机过氧化物
热分解
压力特性
安全性
评价
organic peroxides
heating decomposition
pressure
characteristic
