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还原终温对磷化物催化剂加氢脱硫反应性能的影响 被引量：1

Influence of final reduction temperature on HDS activities of phosphides catalysts
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摘要 以全硅MCM-41为载体,制备负载Ni_2P和MoP型催化剂,考察了还原终温对催化剂制备和加氢脱硫反应性能的影响。对于Ni_2P/MCM-41,NiO负载质量分数为12%,通过XRD和加氢脱硫反应评价得出最佳还原终温为500℃;对于MoP/MCM-41,MoO_3负载质量分数为40%,通过XRD和加氢脱硫反应评价得出最佳还原终温为650℃。 Ni2P and MoP supported MCM-41 catalysts were prepared by temperature-programed reduction procedure. The effects of final reduction temperature on phosphide structure and HDS activities were investigated. The results showed that the optimum final reduction temperature for Ni2P/MCM-41 with NiO loading of 12wt% and MoP/MCM-41 with MoO3 loading of 40wt% were 500 ℃ and 650 ℃respectively by XRD characterization and hydrodesulfurization （HDS） activity evaluation.
作者 杨晓东 李瑞 王登飞 赵檀 张国甲 王安杰 李翔
机构地区 中国石油石油化工研究院大庆化工研究中心 大连理工大学精细化工国家重点实验室
出处 《工业催化》 CAS 2011年第7期46-48,共3页 Industrial Catalysis
关键词 催化剂工程 加氢脱硫 MCM-41 磷化物催化剂 catalyst engineering hydrodesulfurization MCM-41 phosphides catalyst
分类号 TQ426.6 [化学工程] TQ426.95 [化学工程]
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参考文献3

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同被引文献68

  • 1李冬燕,余夕志,陈长林,徐南平.Ni2P/TiO2的制备及其加氢和脱氢性能研究[J].石油化工,2004,33(z1):1405-1407. 被引量：3
  • 2李冬燕,余夕志,陈长林,徐南平,王延儒.Ni_2P/TiO_2上噻吩加氢脱硫性能研究[J].高校化学工程学报,2006,20(5):825-830. 被引量：26
  • 3宋立民,李伟,张明慧,陶克毅.Ni_2P/SiO_2-Al_2O_3催化剂的制备、表征及其对4,6-二甲基二苯并噻吩加氢脱硫反应的催化性能[J].催化学报,2007,28(2):143-147. 被引量：36
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工业催化
2011年 第7期

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