摘要
以Cd(CH3COO)2和烟酸(C6H5O2N)为原料,采用水热法合成了类金刚烷型配位聚合物[Cd(C6H5O2N)2-(H2O)]n,利用元素分析、X射线单晶衍射对其结构进行了表征。该配合物属于正交晶系,Pbca空间群,a=1.144 9(5)nm,b=1.208 3(5)nm,c=1.742 8(5)nm,α=β=γ=90°,V=2.411(16)nm3,Z=8,dc=2.064 g/cm3,μ=1.834 mm-1,F(000)=1 472,R1=0.022 6,wR2=0.041 8。
A novel adamantane-like coordination polymer[Cd(C6H5O2N)2(H2O)]n was synthesized by hydrothermal reaction with Cd(CH3COO)2 and nicotinic acid(C6H5O2N) as raw materials.The structure was characterized by elemental analysis,single crystal X-ray diffraction analysis.The title compound crystallizes in orthorhombic space group Pbca,with a=1.144 9(5)nm,b=1.208 3(5) nm,c=1.742 8(5)nm,α=β=γ=90°,V=2.411(16) nm3,Z=8,dc=2.064 g/cm3,μ=1.834 mm-1,F(000)=1 472,R1=0.022 6,wR2 =0.041 8.
出处
《应用化工》
CAS
CSCD
2011年第7期1159-1161,共3页
Applied Chemical Industry
基金
陕西省重点实验室项目(09JS068)
宝鸡文理学院科研资助项目(ZK1020)
关键词
烟酸
镉
水热合成
晶体结构
nicotinic acid
cadmium
hydrothermal synthesis
crystal structure