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碳酸铅制备铅酸蓄电池电极的研究Ⅰ-电极的活化 被引量:2

Studies of the Electrode Preparation of Electrode from Lead Carbonate for Lead acid Battery Ⅰ The activation of the PME
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摘要 用循环伏安法研究了PbCO3 粉末微电极转化为PbSO4 电极的活化方法和条件.发现在2 ~2-5 mol/LH2SO4 溶液中由PbCO3 转化成PbO2/PbSO4 和PbSO4/Pb 电极时,以不对称交变讯号活化( 化成) 后,其循环伏安性能与由球磨机生产的PbO 粉所制得的相应电极性能相近.对于负极,在含有乙炔黑胶体的H2SO4 溶液中化成,由于碳胶粒在PbSO4 晶体上的吸附,阻止了充放电过程中电极材料的收缩,同时增加了电极的导电性。 Lead carbonate which was an intermediate product in lead hydrometallurgy without pollution of lead vapor and sulfur dioxide was selected as electrode material of lead_acid batteries. In the present work,the performances of PbO 2/PbSO 4 or PbSO 4/Pb electrode transformed from PbCO 3 have been investigated by powder microelectrode technique combined with cyclic voltammetry.The results show that the CV characteristics of either negative or positive electrode prepared from PbCO 3 is as good as that of both electrodes made from lead oxide produced by mill machine,when a powder microelectrode with PbCO 3 transformed into PbSO 4 in 1.0 mol/L H 2SO 4 solution,and then activated to form Pb or PbO 2 using an unsymmetrical interchangeable signal( Q a/ Q c or Q c/ Q a being 0.2~0.4) in 2.0~2.5 mol/L H 2SO 4 solution.Furthermore,comparing the negative electrode activated in 2.5 mol/L H 2SO 4 solution containing 4% carbon colloid with one activated in the same H 2SO 4 solution concentration without ABC,the cyclic voltammetric characteristics of the former has been obviously improved.It is possible that the carbon colloid particles can be adsorbed on PbSO 4 crystals,which could increase the conductivity and reduce the shrinking of the electrode
出处 《电化学》 CAS CSCD 1999年第4期437-442,共6页 Journal of Electrochemistry
基金 国家自然科学基金
关键词 碳酸铅 铅酸蓄电池 粉末微电极 活化 电极 Lead carbonate, Lead_acid battery, Powder microelectrode, Activation
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参考文献7

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共引文献16

同被引文献16

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二级引证文献6

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