摘要
对于新发现的S_2O_8^(2-)-ClO_2^--S^(2-)体系在CSTR实验中铂电位的振荡现象、以及Batch实验中铂电位、pH值的非线性现象进行了报道.分析了该体系的自催化过程,提出了反应的几个步骤所对应的化学方程式,并且对自催化机理进行了初步的分析.
A new oscillatory system of S2O82- ClO2- S2- is reported. The oscillation of Pt potential in CSTR and other nonlinear phenomena of ft potential, and pH value in close (Batch) system are studied. The autocatalytic procedures are analyzed, and the stoichiometric equations of several reaction steps are suggested. The analysis of the autocatalytic mechanism is accomplished.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1999年第12期1319-1324,共6页
Acta Chimica Sinica
基金
国家自然科学基金(29573109)
国家教育部留学归国人员基金资助项目
