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水溶性胺膦配体的合成和应用 被引量：1

PREPARATION AND APPLICATION OF WATER SOLUBLE AMINOPHSOPHINE LIGANDS
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摘要 本文简要叙述了通过胺膦配体中的活泼氨基引入各种极性基团 。 The aminophonphine ligands display important role in coordination and under homogeneous catalysis.Recently,an increasing interest has been directed to water soluble aminophosphine ligands.This review discribes briefly the preparation of various water soluble aminophosphine ligands in which polar functional groups were introduced by active hydrogen on nitrogen atom and their application in homogeneous catalysis or catalytic asymmetric synthesis.
作者 伊晓东 陈守正 高景星 许翩翩
机构地区 福建师范大学化学系 厦门大学化学系
出处 《化学研究与应用》 CAS CSCD 1999年第6期604-609,共6页 Chemical Research and Application
关键词 水溶性 胺膦配体 手征性 不对称催化 催化剂 water soluble,aminophosphine,chiral ligand,asymmetric catalysis
分类号 O627.51 [理学—有机化学] O643.36 [理学—物理化学]
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参考文献2

  • 1黄伟国 钱延龙 等.“金属有机化学与催化”[M].北京:化学工业出版社,1997.446-465.
  • 2黄伟国，金属有机化学与相催化，1997年，446页

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同被引文献28

  • 1Chen Yingchun, Wu Tongfei, Jiang Yaozhong, et al. Synthesis of dendritic catalysts and application in asymmetric transfer hydrogenation[J]. J Org Chem, 2005,70(3) : 1006-1010.
  • 2Chen Yingehun, Wu Tongfei, Deng Jingen, et al. Multiple dendritic catalysts for asymmetric transfer hydrogenation[J]. J Org Chem, 2002,67(15) : 5301-5306.
  • 3Geldbaeh T J, Dyson P J. A versatile ruthenium precursor for biphasic catalysis and its application in ionic liquid biphasic transfer hydrogenation: conventional vs task-specific eatalysts[J]. J Am Chem Soc,2004,126(26):8114-8115.
  • 4Kawasaki I, Tsunoda K, Ohta S, et al. A recyclable catalyst for asymmetric transfer hydrogenation with a formic aeid-triethylamine mixture in ionic liquid[J]. Chem Commun,2005,16:2134-2136.
  • 5Okano K, Murata K, Ikariya T. Stereoselective synthesis of optically active pyridyl alcohols via asymmetric transfer hydrogenation of pyridyl ketones[J]. Tetrahedron Letter,2000,41(48):9277-9280.
  • 6Hansen K B, Chilenski J R, Mathre D J, et al. Scalable, efficient process for the synthesis of(R)-3,5-bistrifluoromethylphenyl ethanol via catalytic asymmetric transfer hydrogenation and isolation as a DABCO inclusion complex[J]. Tetrahedron: Asymmetry, 2003,14 (22) :3581-3587.
  • 7Hashiguchi S, Ikariya T, Noyori R, et al. Asymmetric transfer hydrogenation of aromatic ketones catalyzed bychiral ruthenium(Ⅱ) complexes[J]. J Am Chem Soc, 1995,117(28) :7562-7563.
  • 8Blaser H U,Schmidt E.工业规模的不对称催化[M].上海:华东理工大学出版社,2006:189-203.
  • 9Murata K, Ikariya T, Noyori R. New chiral rhodium and iridium complexes with chiral diamine ligands for asymmetric transfer hydrogenation of aromatic ketones[J]. J Org Chem,1999,64(7):2186-2187.
  • 10Ikariya T, Blacker A J. Asymmetric transfer hydrogenation of ketones with bifunctional transition metal-based molecular catalysts[J]. Acc Chem Res, 2007,40 : 1300-1308.

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化学研究与应用
1999年 第6期

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