摘要
C_(60)与乙醇胺反应,然后与亚氯铂酸钾络合,制得了含配位氮原子的富勒烯铂配合物。该配合物能有效地催化烯烃与三乙氧基硅烷的硅氢化反应,并对苯乙烯有独特的催化性能,以近100％的区域选择性得到α-加成产物。还对催化机理进行了初步的探讨。
Fullerene ethanolamine platinum complex was prepared by reacting Ceo ethanolamine, potassium chloroplatinite sequentialy. The complex was an effective catalyst for hydrosilylation of olefins with triethoxysilane. Interestingly, it exhibits nearly 100% regioselectivity for styrene a - adduct. The mechanism of hydrosilylation was also investigated.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1999年第6期600-605,共6页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金
关键词
碳60
铂配合物
富勒烯
硅氢化
催化剂
f ullerene, hydrosilylation catalyst, regioselectivity, mechanism
