摘要
本文综述了近年来由三中心氢键和远程位阻效应促进的环芳酰胺合成及该类化合物自组装行为的研究进展.在研究一步高效成环的基础上,对合成不同孔径刚性大环分子的方法进行了探讨.改变大环分子周边侧链极性可以调控这类大环分子的自组装行为.探讨了环芳酰胺的应用及发展前景.
There has been a great interest in the creation of organic nanometer functional materials based on self-assembly of shape-persistent macrocycles via noncovalent interaction due to numerous potential applications in biology,chemistry and material sicence.In this review,we summarize the recent progress in synthesis of cycloaramides assisted by three-center hydrogen bonding and the remote steric effect,and their self-assembly behavior of these macrocycles.The strategies for preparing shape-persistent aromatic oligoamide macrocycles with different cavity sizes were discussed based on the highly efficient,one-step macrocyclization.The self-assembly properties of these cycles can be manipulated by means of altering side chains on the periphery.A brief account of cycloaramides with some applications was given,and their developing trends were also proposed.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2011年第9期1950-1961,共12页
Chemical Journal of Chinese Universities
基金
国家自然科学基金(批准号:20774059
20672078)
教育部博士学科点基金(批准号:20090181110047)资助
关键词
环芳酰胺
刚性大环
三中心氢键
自组装
Cycloaramide
Shape-persistent macrocycle
Three-center hydrogen bond
Self-assembly
