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Facile synthesis of hypercrosslinked resin via photochlorination of p-xylene and succedent alkylation polymerization 被引量:2

Facile synthesis of hypercrosslinked resin via photochlorination of p-xylene and succedent alkylation polymerization
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摘要 A combination of photochlorination ofp-xylene and succedent Friedel-Crafts alkylation polymerization was firstly used in the preparation of the hypercrosslinked adsorptive resin. The data of GC-MS and GC showed that a series of chlorizates were produced when p-xylene was photochlorinated. Hypercrosslinked resins could be synthesized by copolymerization, self-polymerization of chlorizates or post crosslinking reaction. The chemical structure and micromorphology of the porous resins were characterized by BET, FF-IR, SEM and elementary analysis (EA). The results showed that the novel adsorptive resins possess high BET surface near to 1038 m^2/g and large pore volumes range from 0.5 to 1.2 cm^3/g. A combination of photochlorination ofp-xylene and succedent Friedel-Crafts alkylation polymerization was firstly used in the preparation of the hypercrosslinked adsorptive resin. The data of GC-MS and GC showed that a series of chlorizates were produced when p-xylene was photochlorinated. Hypercrosslinked resins could be synthesized by copolymerization, self-polymerization of chlorizates or post crosslinking reaction. The chemical structure and micromorphology of the porous resins were characterized by BET, FF-IR, SEM and elementary analysis (EA). The results showed that the novel adsorptive resins possess high BET surface near to 1038 m^2/g and large pore volumes range from 0.5 to 1.2 cm^3/g.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2011年第9期1115-1118,共4页 中国化学快报(英文版)
基金 support of the National Natural Science Foundation of China(Nos.20574063 and 21004055)
关键词 Hypercrosslinked resin SYNTHESIS P-XYLENE PHOTOCHLORINATION POLYMERIZATION Hypercrosslinked resin Synthesis p-Xylene Photochlorination Polymerization
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