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气相色谱-场电离飞行时间质谱测定柴油馏分中含硫化合物的形态分布 被引量:9

Distribution of Sulfur Compounds in Diesel Oil by GC Field Ionization Time-of-Flight High-Resolution Mass Spectrometry
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摘要 采用气相色谱-场电离飞行时间质谱(GC-FI TOF HRMS)建立了柴油中含硫化合物形态分布的测定方法。该方法无需对样品中的含硫化合物进行分离富集,可直接进样分析,能够提供7类含硫化合物的类型和碳数分布的信息。 GC separation,field ionization and time-of-flight high-resolution mass spectrometry(GC-FI TOF HRMS) were combined for detailed analysis of sulfur compounds in diesel oil.With this new method the samples needed not to be pre-separated,and could directly be injected for analysis.For a single analysis,the information of carbon number and compound-type distribution of seven kinds of sulfur compounds could be obtained.
出处 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2011年第5期797-800,共4页 Acta Petrolei Sinica(Petroleum Processing Section)
基金 国家重点基础研究发展计划"973"项目(2006CB202501)资助
关键词 气相色谱 场电离 飞行时间高分辨质谱(TOF HRMS) 柴油 含硫化合物 碳数分布 gas chromatography field ionization time-of-flight high-resolution mass spectrometry(TOF HRMS) diesel oil sulfur compound carbon number distribution
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